PROTONATION OF THE AMINE NITROGENS IN EMERALDINE - EVIDENCE FROM X-RAY PHOTOELECTRON-SPECTROSCOPY

被引：39

作者：

KANG, ET ^{[1
]}

NEOH, KG ^{[1
]}

TAN, KL ^{[1
]}

TAN, BTG ^{[1
]}

机构：

[1] NATL UNIV SINGAPORE,DEPT PHYS,SINGAPORE 0511,SINGAPORE

来源：

SYNTHETIC METALS | 1992年 / 46卷 / 02期

关键词：

EMERALDINE; PROTONATION; AMINE NITROGENS; NONVOLATILE ACIDS; XPS;

D O I：

10.1016/0379-6779(92)90346-K

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

The protonations of the emeraldine (EM) oxidation state of polyaniline (PAN) by non-volatile protonic acids, such as H2SO4 and HClO4, have been studied by X-ray photoelectron spectroscopy (XPS). The properly resolved N(1s) core-level spectra reveal that a large proportion of the amine nitrogens in the EM base powders and films is also susceptible to protonation when the samples are loaded with excessive non-volatile acids.

引用

页码：227 / 233

页数：7

共 16 条

[11]

Skotheim T. A., 1986, HDB CONDUCTING POLYM, V2

[12] A PHOTOELECTRON SPECTROSCOPIC STUDY OF THE ELECTROCHEMICAL PROCESSES IN POLYANILINE [J].