RELATIVE PHOTOIONIZATION CROSS-SECTION STUDY OF OH AND OD FROM 68 NM TO 95 NM

被引:17
作者
CUTLER, JN [1 ]
HE, ZX [1 ]
SAMSON, JAR [1 ]
机构
[1] UNIV NEBRASKA,DEPT PHYS,LINCOLN,NE 68588
关键词
D O I
10.1088/0953-4075/28/21/007
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
The photoionization spectra of OH and OD have been reported from 680 to 950 Angstrom (18.23 to 13.05 eV) at a wavelength resolution of 0.07 Angstrom. Through interpretation of both spectra, the Rydberg series and their higher vibrational members have been reported for three of the excited ionic states, a (1) Delta, A (3) Pi(i), and b (1) Sigma(+). A vibrational progression has also been observed in both OH and OD which is apparently related to a fourth excited ionic state, c (1) Pi. Finally, the dissociative ionization limits, corrected to 0 K, for H2O and D2O have been measured to be 18.11 +/- 0.01 and 18.21 +/- 0.01 eV, respectively, and shown to be in good agreement with previously reported results.
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页码:4577 / 4591
页数:15
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