PREPARATION AND REACTIVITY OF THE FIRST YTTRIUM PORPHYRINOGEN COMPLEX

被引：35

作者：

JUBB, J

GAMBAROTTA, S

DUCHATEAU, R

TEUBEN, JH

机构：

[1] UNIV OTTAWA,DEPT CHEM,OTTAWA K1N 6N5,ON,CANADA

[2] UNIV GRONINGEN,CTR CATALYSIS & SYNTH,DEPT CHEM,9747 AG GRONINGEN,NETHERLANDS

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 22期

关键词：

D O I：

10.1039/c39940002641

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reaction of Li-4(thf)(4)(oepg) (oepg = octaethylporphyrinogen with YCl3(thf)(3.5) affords the first yttrium porphyrinogen complex [Li(thf)(2)][(oepg)Y(mu-OEt)Li(thf)] 1 via intermediate cleavage of thf, subsequent reaction with alkyl and hydride sources leads to the formation of the demetallated dienolate salt of the macrocycle [(oepg)(thfLi)(4)][(thf)LiOCH=CH2](2) 2.

引用

页码：2641 / 2642

页数：2

共 26 条

[1] METAL-COMPLEXES WITH TETRAPYRROLE LIGANDS .67. SYNTHESIS AND SPECTROSCOPIC PROPERTIES OF WATER-SOLUBLE CERIUM BISPORPHYRINATE DOUBLE-DECKER IONS
BUCHLER, JW
NAWRA, M
[J]. INORGANIC CHEMISTRY, 1994, 33 (13) : 2830 - 2837
[2] REACTIONS OF YTTRIUM CARBON BONDS WITH ACTIVE HYDROGEN-CONTAINING MOLECULES - A USEFUL SYNTHETIC METHOD FOR PERMETHYLYTTROCENE DERIVATIVES
DENHAAN, KH
WIELSTRA, Y
TEUBEN, JH
[J]. ORGANOMETALLICS, 1987, 6 (10) : 2053 - 2060
[3] BIS(TRIMETHYLSILYL)BENZAMIDINATE - A PROMISING SPECTATOR LIGAND IN ORGANOYTTRIUM CHEMISTRY - SYNTHESIS AND REACTIVITY OF ([C6H5C(NSIME3)2]2Y-MU-R)2(R = H, CCH) AND X-RAY STRUCTURE OF ([C6H5C(NSIME3)2]2Y-MU-CCH)2
DUCHATEAU, R
VANWEE, CT
MEETSMA, A
TEUBEN, JH
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (11) : 4931 - 4932
[4] GILLARD RD, 1987, COMPREHENSIVE COORDI, V3
[5] ALKENE AND ALKYNE INSERTION REACTIONS OF CATIONIC CP2ZR(ETA-2-PYRIDYL)(L)+ COMPLEXES - ZIRCONIUM-MEDIATED FUNCTIONALIZATION OF PYRIDINES
GURAM, AS
JORDAN, RF
[J]. ORGANOMETALLICS, 1991, 10 (10) : 3470 - 3479
[6] CATALYTIC OLIGOMERIZATION OF TERMINAL ALKYNES BY LANTHANIDE CARBYLS (ETA-5-C5ME5)2LNCH(SIME3)2 (LN=Y,LA,CE)
HEERES, HJ
TEUBEN, JH
[J]. ORGANOMETALLICS, 1991, 10 (06) : 1980 - 1986
[7] HIGHLY REACTIVE ORGANOLANTHANIDES - A MECHANISTIC STUDY OF CATALYTIC OLEFIN HYDROGENATION BY BIS(PENTAMETHYLCYCLOPENTADIENYL) AND RELATED 4F COMPLEXES
JESKE, G
LAUKE, H
MAUERMANN, H
SCHUMANN, H
MARKS, TJ
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (26) : 8111 - 8118
[8] SYNTHESIS AND INSERTION CHEMISTRY OF CATIONIC ZIRCONIUM(IV) PYRIDYL COMPLEXES - PRODUCTIVE SIGMA-BOND METATHESIS
JORDAN, RF
TAYLOR, DF
BAENZIGER, NC
[J]. ORGANOMETALLICS, 1990, 9 (05) : 1546 - 1557
[9] PREPARATION AND CHARACTERIZATION OF THE 1ST VANADIUM YNOLATE COMPLEX
JUBB, J
GAMBAROTTA, S
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (22) : 10410 - 10411
[10] THE SURPRISING ROLE OF THF IN VANADIUM MACROCYCLIC CHEMISTRY
JUBB, J
GAMBAROTTA, S
[J]. INORGANIC CHEMISTRY, 1994, 33 (12) : 2503 - 2504

← 1 2 3 →