PREPARATION AND REACTIVITY OF THE FIRST YTTRIUM PORPHYRINOGEN COMPLEX

被引:35
作者
JUBB, J
GAMBAROTTA, S
DUCHATEAU, R
TEUBEN, JH
机构
[1] UNIV OTTAWA,DEPT CHEM,OTTAWA K1N 6N5,ON,CANADA
[2] UNIV GRONINGEN,CTR CATALYSIS & SYNTH,DEPT CHEM,9747 AG GRONINGEN,NETHERLANDS
关键词
D O I
10.1039/c39940002641
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Reaction of Li-4(thf)(4)(oepg) (oepg = octaethylporphyrinogen with YCl3(thf)(3.5) affords the first yttrium porphyrinogen complex [Li(thf)(2)][(oepg)Y(mu-OEt)Li(thf)] 1 via intermediate cleavage of thf, subsequent reaction with alkyl and hydride sources leads to the formation of the demetallated dienolate salt of the macrocycle [(oepg)(thfLi)(4)][(thf)LiOCH=CH2](2) 2.
引用
收藏
页码:2641 / 2642
页数:2
相关论文
共 26 条
[11]   DINITROGEN REDUCTION OPERATED BY A SAMARIUM MACROCYCLIC COMPLEX - ENCAPSULATION OF DINITROGEN INTO A SM2LI4 METALLIC CAGE [J].
JUBB, J ;
GAMBAROTTA, S .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (10) :4477-4478
[12]   H-H AND C-H ACTIVATION REACTIONS AT DO METAL CENTERS [J].
RABAA, H ;
SAILLARD, JY ;
HOFFMANN, R .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1986, 108 (15) :4327-4333
[13]   INSERTION, H/D EXCHANGE, AND SIGMA-BOND METATHESIS REACTIONS OF ACETYLENE WITH CL2SCH [J].
RAPPE, AK .
ORGANOMETALLICS, 1990, 9 (02) :466-475
[14]   LANTHANIDES AND ACTINIDES - ANNUAL SURVEY COVERING THE YEAR 1991 [J].
ROGERS, RD ;
ROGERS, LM .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1993, 457 (1-2) :41-62
[15]   CHEMISTRY OF (OCTAETHYLPORPHYRINATO)LUTETIUM AND (OCTAETHYLPORPHYRINATO)YTTRIUM COMPLEXES - SYNTHESIS AND REACTIVITY OF (OEP)MX DERIVATIVES AND THE SELECTIVE ACTIVATION OF O2 BY (OEP)Y(MU-ME)2ALME2 [J].
SCHAVERIEN, CJ ;
ORPEN, AG .
INORGANIC CHEMISTRY, 1991, 30 (26) :4968-4978
[17]   2S + 2S REACTIONS AT TRANSITION-METALS .1. THE REACTIONS OF D2 WITH CL2TIH+, CL2TIH, AND CL2SCH [J].
STEIGERWALD, ML ;
GODDARD, WA .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1984, 106 (02) :308-311
[18]   ALPHA-BOND METATHESIS FOR C-H BONDS OF HYDROCARBONS AND SC-H, SC-ALKYL, SC-ARYL BONDS OF PERMETHYLSCANDOCENE DERIVATIVES - EVIDENCE FOR NONINVOLVEMENT OF THE PI-SYSTEM IN ELECTROPHILIC ACTIVATION OF AROMATIC AND VINYLIC C-H BONDS [J].
THOMPSON, ME ;
BAXTER, SM ;
BULLS, AR ;
BURGER, BJ ;
NOLAN, MC ;
SANTARSIERO, BD ;
SCHAEFER, WP ;
BERCAW, JE .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (01) :203-219
[19]   SOME ASPECTS OF THE CHEMISTRY OF ALKYL AND HYDRIDE DERIVATIVES OF PERMETHYLSCANDOCENE [J].
THOMPSON, ME ;
BERCAW, JE .
PURE AND APPLIED CHEMISTRY, 1984, 56 (01) :1-11
[20]   THE ACTIVATION OF SMALL MOLECULES BY DINUCLEAR COMPLEXES OF COPPER AND OTHER METALS [J].
VIGATO, PA ;
TAMBURINI, S ;
FENTON, DE .
COORDINATION CHEMISTRY REVIEWS, 1990, 106 :25-170