PREPARATION AND REACTIVITY OF THE FIRST YTTRIUM PORPHYRINOGEN COMPLEX

被引：35

作者：

JUBB, J

GAMBAROTTA, S

DUCHATEAU, R

TEUBEN, JH

机构：

[1] UNIV OTTAWA,DEPT CHEM,OTTAWA K1N 6N5,ON,CANADA

[2] UNIV GRONINGEN,CTR CATALYSIS & SYNTH,DEPT CHEM,9747 AG GRONINGEN,NETHERLANDS

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 22期

关键词：

D O I：

10.1039/c39940002641

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reaction of Li-4(thf)(4)(oepg) (oepg = octaethylporphyrinogen with YCl3(thf)(3.5) affords the first yttrium porphyrinogen complex [Li(thf)(2)][(oepg)Y(mu-OEt)Li(thf)] 1 via intermediate cleavage of thf, subsequent reaction with alkyl and hydride sources leads to the formation of the demetallated dienolate salt of the macrocycle [(oepg)(thfLi)(4)][(thf)LiOCH=CH2](2) 2.

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页码：2641 / 2642

页数：2

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