REACTION OF CH2(PH(2)PSE)(2) WITH [RU-3(CO)(12)] - CRYSTAL-STRUCTURE OF [RU4SE4(CO)(10)(PH(2)PCH(2)PPH(2))], A MISSING LINK IN THE [M(4)E(4)L(12)] CUBANE SERIES (M=GROUP-8 METAL, E=CHALCOGENIDO LIGAND)

被引：37

作者：

CAUZZI, D ^{[1
]}

GRAIFF, C ^{[1
]}

LANFRANCHI, M ^{[1
]}

PREDIERI, G ^{[1
]}

TIRIPICCHIO, A ^{[1
]}

机构：

[1] UNIV PARMA,DIPARTIMENTO CHIM GEN & INORGAN CHIM ANALIT CHIM FIS,CNR,I-43100 PARMA,ITALY

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1995年 / 13期

关键词：

D O I：

10.1039/dt9950002321

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The bis(phosphine selenide) CH2(Ph(2)PSe)(2) and [RU(3)(CO)(12)] (1:1) reacted in toluene to give [Ru-3(mu(3)-Se)(2)(CO)(7)(dppm)], [Ru-4(mu(4)-Se)(2)(CO)(9)(dppm)] and [Ru-4(mu(3)-Se)(4)(CO)(10)(dppm)] (dppm = Ph(2)PCH(2)-PPh(2)), the last of which is the first reported 72-electron Ru-Se cubane-like cage complex.

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页码：2321 / 2322

页数：2

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