ETHYL CYANOFORMATE HYDROGEN-PEROXIDE AND RELATED COMBINATION SYSTEMS, NOVEL EPOXIDIZING SYSTEMS OF OLEFINS

被引：13

作者：

MASAKI, Y

MIURA, T

MUKAI, I

ITOH, A

ODA, H

机构：

来源：

CHEMISTRY LETTERS | 1991年 / 11期

关键词：

D O I：

10.1246/cl.1991.1937

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A combination system of ethyl cyanoformate and hydrogen peroxide was found to epoxidize olefins in a stereospecific manner at room temperature. Asymmetric epoxidation was observed with menthyl cyanoformate/hydrogen peroxide system.

引用

页码：1937 / 1940

页数：4

共 26 条

[21] PROGRESS IN THE DEVELOPMENT OF NEW EPOXIDATION REAGENTS [J].

REBEK, J .

HETEROCYCLES, 1981, 15 (01) :517-545

[22] A VERY EFFICIENT SYSTEM FOR ALKENE EPOXIDATION BY HYDROGEN-PEROXIDE - CATALYSIS BY MANGANESE-PORPHYRINS IN THE PRESENCE OF IMIDAZOLE [J].

RENAUD, JP ;

BATTIONI, P ;

BARTOLI, JF ;

MANSUY, D .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1985, (13) :888-889

[23]

Sharpless K. B., 1979, ALDRICHIM ACTA, V12, P63

[24] EPOXIDATION OF OLEFINS BY HYDROGEN-PEROXIDE IN THE PRESENCE OF TETRACHLOROACETONE [J].

STARK, CJ .

TETRAHEDRON LETTERS, 1981, 22 (22) :2089-2092

[25]

TERAO S, 1979, SYNTHESIS-STUTTGART, P467

[26] ENANTIOSELECTIVE EPOXIDATION OF UNFUNCTIONALIZED OLEFINS CATALYZED BY (SALEN)MANGANESE COMPLEXES [J].

ZHANG, W ;

LOEBACH, JL ;

WILSON, SR ;

JACOBSEN, EN .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (07) :2801-2803

← 1 2 3 →