GENERATION OF AMINYL RADICALS USING SULFENAMIDES AS SYNTHETIC PRECURSORS

被引：71

作者：

BOWMAN, WR

CLARK, DN

MARMON, RJ

机构：

[1] Department of Chemistry, University of Technology, Loughborough,

来源：

TETRAHEDRON | 1994年 / 50卷 / 04期

关键词：

SULFENAMIDES; AMINYL RADICALS; TRIBUTYLTIN HYDRIDE; RADICAL-CYCLIZATION; N-(BENZENESULFENYL)PHTHALIMIDE;

D O I：

10.1016/S0040-4020(01)80837-1

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Sulfenamides are synthesised from reaction between amines and N-(benzenesulfenyl)-phthalimide or benzenesulfenyl chloride. The sulfenamides undergo reaction with tributyltin hydride to yield aminyl radicals which can be cyclised onto suitable alkenes.

引用

页码：1275 / 1294

页数：20

共 60 条

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