ORGANOMETALLIC COMPOUNDS OF LANTHANOIDS .98. SYNTHESIS AND STRUCTURAL ELUCIDATION OF DICHLORO-(ETA(5)-2,5-DI-TERT-BUTYLPYRROLYL)BIS(TETRAHYDROFURAN)YTTERBIUM(III)

被引：27

作者：

SCHUMANN, H

ROSENTHAL, ECE

WINTERFELD, J

KOCIOKKOHN, G

机构：

[1] Institut für Anorganische, Analytische Chemie der Technischen Universität Berlin, 10623 Berlin

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1995年 / 495卷 / 1-2期

关键词：

YTTERBIUM; CRYSTAL STRUCTURE;

D O I：

10.1016/0022-328X(95)05495-B

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction between YbCl3(THF)(3) and Na[pyr*](pyr*=NC(4)H(2)(t)Bu(2)-2,5) yields the monopyrrolyl complex, [(pyr*)YbCl2(THF)(2)] (1). The X-ray structure of compound 1 confirms the pi-coordination between the metal and the azacyclopentadienyl ligand.

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页码：C12 / C14

页数：3

相关论文

共 16 条

[1] STRUCTURE AND REACTIVITY OF COORDINATIVE OVERLOADED DICHLORO-ETA-5-CYCLOPENTADIENYL TRIS (TETRAHYDROFURAN)YTTERBIUM (III) COMPLEXES [J].

ADAM, M ;

LI, XF ;

OROSCHIN, W ;

FISCHER, RD .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1985, 296 (03) :C19-C22

[2]

BELSKII VK, 1989, ORGANOMET CHEM USSR, V2, P286

[3] CRYSTAL-STRUCTURE OF TRICHLOR-[2,5-DI-TERT-BUTYL-3-TRIMETHYL-SILYLPYRROLYL]-TITANIUM(IV), C15H28CL3NSITI [J].

BOESE, R ;

BLASER, D ;

KUHN, N ;

STUBENRAUCH, S .

ZEITSCHRIFT FUR KRISTALLOGRAPHIE, 1994, 209 (02) :188-188

[4] HETEROCYCLES AS LIGANDS .14. 2,2',5,5'-TETRA-TERT-BUTYL-1,1'-DIAZAPLUMBOCENE - A STABLE AZACYCLOPENTADIENYL COMPOUND OF LEAD [J].

KUHN, N ;

HENKEL, G ;

STUBENRAUCH, S .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1992, 31 (06) :778-779

[5] HETEROCYCLES AS LIGANDS .10. 2,2',5,5'-TETRA-TERT-BUTYL-1,1'-DIAZAFERROCENE - STABILIZATION OF THE DIHETEROMETALLOCENE STRUCTURE BY STERIC SHIELDING [J].

KUHN, N ;

JENDRAL, K ;

BOESE, R ;

BLASER, D .

CHEMISCHE BERICHTE, 1991, 124 (01) :89-91

[6] HETEROCYCLES AS LIGANDS - (2,5-C4H2BU-TERT2N)2CO - THE 1ST DIAZACOBALTOCENE [J].

KUHN, N ;

KOCKERLING, M ;

STUBENRAUCH, S ;

BLASER, D ;

BOESE, R .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1991, (19) :1368-1370

[7] HETEROCYCLES AS LIGANDS .19. THE ELECTRONIC-STRUCTURE OF 1,1'-DIAZAMETALLOCENES AND THE SYNTHESIS AND CRYSTAL-STRUCTURE OF 2,2',5,5'-TETRA-TERT-BUTYL-1,1'-DIAZANICKELOCENE [J].

KUHN, N ;

HENKEL, G ;

KREUTZBERG, J ;

STUBENRAUCH, S ;

JANIAK, C .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1993, 456 (01) :97-106

[8] HETEROCYCLES AS LIGANDS .16. (2,5-C4TBU2RHN)MCL3 (M = TI, ZR, HF) R = H, SIME3) - AZACYCLOPENTADINYL COMPLEXES OF GROUP-4 METALS [J].

KUHN, N ;

STUBENRAUCH, S ;

BOESE, R ;

BLASER, D .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1992, 440 (03) :289-296

[9] (2,5-C4(BU-TERT)2H2N)2SN - A NEW HETEROSTANNOCENE [J].

KUHN, N ;

HENKEL, G ;

STUBENRAUCH, S .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1992, (10) :760-761

[10]

KUHN N, 1992, ANGEW CHEM, V104, P766