FORMATION OF TRISACCHARIDES (KESTOSES) BY PYROLYSIS OF SUCROSE

被引:24
作者
MANLEYHARRIS, M [1 ]
RICHARDS, GN [1 ]
机构
[1] UNIV MONTANA,WOOD CHEM LAB,MISSOULA,MT 59812
关键词
D O I
10.1016/0008-6215(91)89045-H
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
Amorphous sucrose, containing citric acid as catalyst, undergoes thermolysis at 100-degrees to yield fructofuranosyl cation and D-glucose. The cation reacts with unchanged sucrose to form all three of the known kestoses, and also their alpha-fructofuranosyl anomers. Two of the latter are resistant to invertase hydrolysis. A new fructosylglucose disaccharide is also formed.
引用
收藏
页码:101 / 113
页数:13
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