FORMATION OF TRISACCHARIDES (KESTOSES) BY PYROLYSIS OF SUCROSE

被引:24
作者
MANLEYHARRIS, M [1 ]
RICHARDS, GN [1 ]
机构
[1] UNIV MONTANA,WOOD CHEM LAB,MISSOULA,MT 59812
关键词
D O I
10.1016/0008-6215(91)89045-H
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
Amorphous sucrose, containing citric acid as catalyst, undergoes thermolysis at 100-degrees to yield fructofuranosyl cation and D-glucose. The cation reacts with unchanged sucrose to form all three of the known kestoses, and also their alpha-fructofuranosyl anomers. Two of the latter are resistant to invertase hydrolysis. A new fructosylglucose disaccharide is also formed.
引用
收藏
页码:101 / 113
页数:13
相关论文
共 31 条
[11]   MECHANISIM OF FRUCTOSAN METABOLISM IN HIGHER PLANTS AS EXEMPLIFIED IN HELIANTHUS TUBEROSUS [J].
EDELMAN, J ;
JEFFORD, TG .
NEW PHYTOLOGIST, 1968, 67 (03) :517-+
[12]  
HIDAKA H, 1988, AGR BIOL CHEM TOKYO, V52, P1181
[13]  
HIDAKA H, 1986, Patent No. 8616262
[14]   ISOLATION OF KESTOSES AND NYSTOSE FROM ENZYME DIGESTS BY HIGH-PERFORMANCE LIQUID-CHROMATOGRAPHY [J].
IVIN, PC ;
CLARKE, ML .
JOURNAL OF CHROMATOGRAPHY, 1987, 408 :393-398
[15]   MANIFESTATION OF ANOMERIC FORM, RING STRUCTURE, AND LINKAGE IN THE C-13-NMR SPECTRA OF OLIGOMERS AND POLYMERS CONTAINING D-FRUCTOSE - MALTULOSE, ISOMALTULOSE, SUCROSE, LEUCROSE, 1-KESTOSE, NYSTOSE, INULIN, AND GRASS LEVAN [J].
JARRELL, HC ;
CONWAY, TF ;
MOYNA, P ;
SMITH, ICP .
CARBOHYDRATE RESEARCH, 1979, 76 (NOV) :45-57
[16]  
Kandler O., 1982, Encyclopedia of plant physiology. New series. Volume 13 A. Plant carbohydrates.I. Intracellular carbohydrates [Loewus, R.A.
[17]  
Tanner, W. (Editors)], P348
[18]   MASS SPECTROMETRY OF TRIMETHYLSILYL ETHERS OF 2-KETOHEXOSES [J].
KARADY, S ;
PINES, SH .
TETRAHEDRON, 1970, 26 (19) :4527-&
[19]  
Khan R., 1976, ADV CARBOHYD CHEM BI, V33, P236
[20]   MASS SPECTROMETRY OF METHYLATED METHYL GLYCOSIDES - PRINCIPLES AND ANALYTICAL APPLICATION [J].
KOCHETKO.NK ;
CHIZHOV, OS .
TETRAHEDRON, 1965, 21 (08) :2029-&