AN EXTREMELY EFFICIENT WAY TO PREPARE CONJUGATED CARBONYL-COMPOUNDS FROM TERMINAL ALKENES VIA THE REACTIONS OF OZONIDES, TRIETHYLAMINE AND STABLE PHOSPHORUS YLIDES

被引：18

作者：

HON, YS

LU, L

机构：

[1] Institute of Chemistry, Academia Sinica, Nankang

来源：

TETRAHEDRON | 1995年 / 51卷 / 29期

关键词：

D O I：

10.1016/0040-4020(95)00431-7

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Ozonides derived from mono- and 1,1-di-substituted olefins reacted with triethylamine in the presence of nucleophiles, such as phosphorus ylide or phosphonoacetate to give conjugated carbonyl compounds almost instantaneously in excellent yields. These transformations were accelerated by the by-product (i.e. thermal energy and ammonium formate) generated in the reaction.

引用

页码：7937 / 7942

页数：6

共 16 条

[1]

Bailey P. S., 1978, OZONATION ORGANIC CH, V1

[2]

Bailey P.S, 1982, OZONATION ORGANIC CH, V2

[3] NOTE SUR LA CATALYSE ACIDE DE LA REACTION DES PHOSPHOBETAINES AVEC LE BENZALDEHYDE [J].