MECHANISTIC STUDIES OF 19-ELECTRON ORGANOMETALLIC COMPLEXES - SYNTHESIS OF STABLE 19-ELECTRON COMPLEXES

被引：40

作者：

TYLER, DR

MAO, F

机构：

[1] Department of Chemistry, University of Oregon, Oregon U.S.A., Eugene

来源：

COORDINATION CHEMISTRY REVIEWS | 1990年 / 97卷

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/0010-8545(90)80084-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Evidence for the existence of photochemically generated 19-electron complexes is reviewed. The synthesis of the stable 19-electron (18+δ) Cp′Mo(CO)2(L2-P,P′) complex is described (Cp′ = η5-C5Ph4H: L2 = 2,3-bis(diphenylphosphino) maleic anhydride). The spectroscopic properties of this complex are reported and discussed. © 1990.

引用

收藏

页码：119 / 140

页数：22

相关论文

共 35 条

[1] ELECTRON-SPIN RESONANCE STUDIES OF METAL-METAL AND METAL-HALOGEN BONDING IN MANGANESE CARBONYLS [J].

ANDERSON, OP ;

SYMONS, MCR .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1972, (18) :1020-&

[2] SPECTROSCOPIC AND THEORETICAL INVESTIGATIONS OF THE INTERLIGAND CHARGE-TRANSFER OF NICKEL(II) MIXED-LIGAND COMPLEXES WITH DITHIOLATE AND ALPHA-DIIMINE LIGANDS [J].

BENEDIX, R ;

PITSCH, D ;

SCHONE, K ;

HENNIG, H .

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1986, 542 (11) :102-116

[3]

CASTELLANI MP, IN PRESS ORGANOMETAL

[4] ORGANOMETALLIC ELECTROCHEMISTRY .6. ELECTROCHEMICAL SCISSION OF METAL-METAL BONDS [J].

DESSY, RE ;

WEISSMAN, PM ;

POHL, RL .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1966, 88 (22) :5117-&

[5] REACTION-MECHANISMS OF METAL-METAL BONDED CARBONYLS - SUBSTITUTION VIA HOMOLYTIC FISSION [J].

FAWCETT, JP ;

JACKSON, RA ;

POE, A .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1975, (18) :733-734

[6] SYNTHESIS, PROPERTIES, AND CRYSTAL-STRUCTURES OF PARAMAGNETIC CARBONYL DERIVATIVES OF COBALT AND MANGANESE WITH 2,3-BIS(DIPHENYLPHOSPHINO)MALEIC ANHYDRIDE AND RELATED PHOSPHINES AS LIGANDS [J].

FENSKE, D .

CHEMISCHE BERICHTE-RECUEIL, 1979, 112 (01) :363-375

[7] ASSOCIATIVE SUBSTITUTION-REACTIONS OF .RE(CO)5 [J].

FOX, A ;

MALITO, J ;

POE, A .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1981, (20) :1052-1053

[8] 19-ELECTRON SPECIES AS INTERMEDIATES IN THE PHOTOCHEMICAL DISPROPORTIONATION OF (ETA-5-CH3C5H4)2MO2(CO)6 [J].

GOLDMAN, AS ;

TYLER, DR .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1984, 106 (14) :4066-4067

[9] CARBONYL-PI-CYCLOPENTADIENYL COMPLEXES OF MOLYBDENUM [J].

HAINES, RJ ;

NYHOLM, RS ;

STIDDARD, MH .

JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1967, (01) :94-&

[10] REACTIONS OF METAL CARBONYL DERIVATIVES .5. REACTION OF BIS(TRICARBONYL-PI-CYCLOPENTADIENYLMOLYBDENUM) WITH TERTIARY ALKYL PHOSPHITES [J].

HAINES, RJ ;

NOLTE, CR .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1970, 24 (03) :725-&

← 1 2 3 4 →