MECHANISTIC STUDIES OF 19-ELECTRON ORGANOMETALLIC COMPLEXES - SYNTHESIS OF STABLE 19-ELECTRON COMPLEXES

被引：40

作者：

TYLER, DR

MAO, F

机构：

[1] Department of Chemistry, University of Oregon, Oregon U.S.A., Eugene

来源：

COORDINATION CHEMISTRY REVIEWS | 1990年 / 97卷

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/0010-8545(90)80084-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Evidence for the existence of photochemically generated 19-electron complexes is reviewed. The synthesis of the stable 19-electron (18+δ) Cp′Mo(CO)2(L2-P,P′) complex is described (Cp′ = η5-C5Ph4H: L2 = 2,3-bis(diphenylphosphino) maleic anhydride). The spectroscopic properties of this complex are reported and discussed. © 1990.

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页码：119 / 140

页数：22

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