TETRATHIAFULVALENE AS A TRIGGER FOR SEQUENTIAL RADICAL TRANSLOCATION AND FUNCTIONALIZATION

被引：14

作者：

BEGLEY, MJ ^{[1
]}

MURPHY, JA ^{[1
]}

ROOME, SJ ^{[1
]}

机构：

[1] UNIV NOTTINGHAM,DEPT CHEM,NOTTINGHAM NG7 2RD,ENGLAND

来源：

TETRAHEDRON LETTERS | 1994年 / 35卷 / 46期

关键词：

D O I：

10.1016/S0040-4039(00)78470-X

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Aryl diazonium salts react with tetrathiafulvalene to generate aryl radicals which undergo intramolecular hydrogen atom abstractions; the radicals which result lend to (a) oxidised product or (b) undergo an unprecedented carbon-carbon bond formation with the radical-cation of tetrathiafulvalene.

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收藏

页码：8679 / 8682

页数：4

相关论文

共 21 条

[11] COMPETING RADICAL TRANSLOCATION REACTIONS OF TERTIARY N-(2-BROMOBENZYL)-ACETAMIDES AND N-(8-BROMONAPHTHYL)-ACETAMIDES [J].

DENENMARK, D ;

WINKLER, T ;

WALDNER, A ;

DEMESMAEKER, A .

TETRAHEDRON LETTERS, 1992, 33 (25) :3613-3616

[12] PROTONATED TETRATHIAFULVALENE - PREPARATION, ISOLATION AND CRYSTAL-STRUCTURE OF 2-(1,3-DITHIOL-2-YL)-1,3-DITHIOL-1-IUM TETRAFLUOROBORATE [J].

GIFFARD, M ;

FRERE, P ;

GORGUES, A ;

RIOU, A ;

RONCALI, J ;

TOUPET, L .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1993, (11) :944-945

[13]

KRICHMEYER S, 1983, SYNTHESIS-STUTTGART, P500

[14] A ROUTE TO THE PYRROLIZIDINE RING-SYSTEM USING A NOVEL RADICAL CYCLIZATION [J].

LATHBURY, DC ;

PARSONS, PJ ;

PINTO, I .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1988, (02) :81-82

[15]

MURPHY JA, 1993, J CHEM SOC CHEM COMM, P295

[16]

PRISBE EJ, 1991, 201ST NAT M AM CHEM

[17] MANGANESE(III)-BASED ASYMMETRIC OXIDATIVE FREE-RADICAL CYCLIZATION OF UNSATURATED BETA-KETO SULFOXIDES [J].

SNIDER, BB ;

WAN, BYF ;

BUCKMAN, BO ;

FOXMAN, BM .

JOURNAL OF ORGANIC CHEMISTRY, 1991, 56 (01) :328-334

[18]

SNIDER BB, 1991, J ORG CHEM, V56, P5844

[19] INTRAMOLECULAR ALPHA-AMIDOYL TO ARYL 1,5-HYDROGEN ATOM TRANSFER-REACTIONS - HETEROANNULATION AND ALPHA-NITROGEN FUNCTIONALIZATION BY RADICAL TRANSLOCATION [J].

SNIECKUS, V ;

CUEVAS, JC ;

SLOAN, CP ;

LIU, HT ;

CURRAN, DP .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (02) :896-898

[20] HOMOLYTIC CYCLIZATIONS OF N-CHLOROALKENYLAMINES [J].

STELLA, L .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1983, 22 (05) :337-350