THE BENEFICIAL-EFFECTS OF INTRODUCING SULFUR SUBSTITUENTS INTO HYDROFORMYLATION SUBSTRATES

被引：16

作者：

BROWNING, AF

BACON, AD

WHITE, C

MILNER, DJ

机构：

[1] UNIV SHEFFIELD,DEPT CHEM,SHEFFIELD S3 7HF,S YORKSHIRE,ENGLAND

[2] ZENECA SPECIALTIES,MANCHESTER M9 3DA,ENGLAND

来源：

JOURNAL OF MOLECULAR CATALYSIS | 1993年 / 83卷 / 03期

关键词：

CATALYSIS; HYDROFORMYLATION; RHODIUM; SULFUR; THIOALKENES;

D O I：

10.1016/0304-5102(93)87037-9

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Using RhH(CO) (PPh3)3 thioalkenes, in particular 2-vinylthiophene, PhSCH=CH2 and 2-MeSC6H4CH=CH2, are readily hydroformylated at 35-degrees-C with high regioselectivity (iso:n less-than-or-equal-to 19.5:1) and with no competing hydrogenation.

引用

页码：L11 / L14

页数：4

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