2,2'-BIPYRENYL AND PARA-TERPYRENYL - A NEW-TYPE OF ELECTRONICALLY DECOUPLED OLIGOARYLENE

被引：49

作者：

KREYENSCHMIDT, M ^{[1
]}

BAUMGARTEN, M ^{[1
]}

TYUTYULKOV, N ^{[1
]}

MULLEN, K ^{[1
]}

机构：

[1] MAX PLANCK INST POLYMER RES,D-55128 MAINZ,GERMANY

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1994年 / 33卷 / 19期

关键词：

D O I：

10.1002/anie.199419571

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

By bridging over centers that lie in nodal planes of the frontier orbitals, the electronic decoupling of the pyrene units in the new compounds bipyrenyl 1 and para‐terpyrenyl 2 is achieved. This causes the electronic situation to differ fundamentally from that in biphenyl, oligo(para‐phenylene)s, and related oligoarylenes. R is, for example, n‐pentyl. (Figure Presented.) Copyright © 1994 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：1957 / 1959

页数：3

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