INFRARED-LASER POWERED PYROLYSIS OF TRIETHYLGALLANE - 1ST EVIDENCE FOR A FREE MONOALKYLGALLANE

被引：20

作者：

GRADY, AS ^{[1
]}

MARKWELL, RD ^{[1
]}

RUSSELL, DK ^{[1
]}

机构：

[1] UNIV LEICESTER,DEPT CHEM,LEICESTER LE1 7RH,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1991年 / 01期

关键词：

D O I：

10.1039/c39910000014

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Ethylgallane, characterised by the IR and H-1 NMR spectra of its trimethylamine adduct, has been identified as an intermediate in the infrared laser powered pyrolysis of triethylgallane, providing the first unambiguous evidence for the existence of free monoalkylgallanes.

引用

收藏

页码：14 / 15

页数：2

相关论文

共 14 条

[1] LASER-POWERED HOMOGENEOUS PYROLYSIS OF TRIMETHYLALUMINUM - TRAPPING OF THE DIMETHYLALUMINUM RADICAL [J].

ATIYA, GA ;

GRADY, AS ;

JACKSON, SA ;

PARKER, N ;

RUSSELL, DK .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1989, 378 (03) :307-316

[2] THE MOLECULAR-STRUCTURES OF THE GASEOUS DIMERIC MOLECULES ME2GA(MU-H)2GAME2 AND ME2GA(MU-CL)2GAME2 AS DETERMINED BY ELECTRON-DIFFRACTION [J].

BAXTER, PL ;

DOWNS, AJ ;

GOODE, MJ ;

RANKIN, DWH ;

ROBERTSON, HE .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1990, (09) :2873-2881

[3] THE SYNTHESIS AND PROPERTIES OF DIMETHYLGALLANE - STRUCTURE OF THE DIMER ME2GA(MU-H)2GAME2 IN THE GAS-PHASE AS DETERMINED BY ELECTRON-DIFFRACTION [J].

BAXTER, PL ;

DOWNS, AJ ;

GOODE, MJ ;

RANKIN, DWH ;

ROBERTSON, HE .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1986, (10) :805-806

[4] GALLANE AT LAST - SYNTHESIS AND PROPERTIES OF BINARY GALLIUM HYDRIDE [J].

DOWNS, AJ ;

GOODE, MJ ;

PULHAM, CR .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (05) :1936-1937

[5] ORGANOMETALLIC COMPOUNDS OF GROUP III .2. REACTION OF GALLIUM ALKYLS AND ALKYL HYDRIDES WITH UNSATURATED HYDROCARBONS [J].

EISCH, JJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1962, 84 (20) :3830-&

[6] INFRARED STUDIES OF EXCHANGE AND PYROLYSIS REACTIONS IN MIXTURES OF TRIMETHYLAMINE ALANE AND TRIMETHYLGALLIUM [J].

GRADY, AS ;

MARKWELL, RD ;

RUSSELL, DK ;

JONES, AC .

JOURNAL OF CRYSTAL GROWTH, 1990, 106 (2-3) :239-245

[7] INFRARED LASER-POWERED SYNTHESIS AND PROPERTIES OF DIETHYLGALLANE [J].

GRADY, AS ;

MAPPLEBECK, AL ;

RUSSELL, DK ;

TAYLORSON, MG .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1990, (13) :929-930

[8]

GRADY AS, IN PRESS J CRYST GRO

[9] TRIMETHYLAMINE ADDUCTS OF GALLANE AND TRIDEUTERIOGALLANE [J].

GREENWOOD, NN ;

STORR, A ;

WALLBRIDGE, MGH .

INORGANIC CHEMISTRY, 1963, 2 (05) :1036-&

[10]

MARKOVA VV, 1967, ZH OBSHCH KHIM+, V37, P1662