THE FIRST CHELATING PHOSPHORUS-NITROGEN DIOXO LIGAND - COMPLEXATION OF AN MOO(O-2)(2) FRAGMENT

被引：13

作者：

THIEL, WR

PRIERMEIER, T

BOG, T

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 18期

关键词：

D O I：

10.1039/c39950001871

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

2-Diphenylphosphinoyl-N,N-dimethylaniline is oxidized at nitrogen by a dilute solution of M(2)O(2) in the presence of MoO(O-2)(2).(H2O)(x); the resulting phosphorus-nitrogen dioxo-ligand forms a molybdenum oxobisperoxo complex, which is structurally characterized by single crystal X-ray diffraction.

引用

收藏

页码：1871 / 1872

页数：2

相关论文

共 23 条

[1]

[Anonymous], 1986, ORGANIC SYNTHESIS OX

[2]

BAMBERGER E, 1899, BER, V32, P342

[3]

Fritz HP, 1965, J CHEM SOC, P5210

[4] CRYSTAL AND MOLECULAR STRUCTURE OF 5-CO-ORDINATE HIGH-SPIN COMPLEX [[2-[[2-(DIETHYLAMINO)ETHYL]AMINO]ETHYL]DIPHENYLPHOSPHINE OXIDE] DI-ISOTHIOCYANATOCOBALT(II) [J].

GHILARDI, CA ;

ORLANDIN.AB .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1972, (16) :1698-&

[5] Halogen-metal interconversion with m- and p-bromodimethylanilines [J].

Gilman, H ;

Banner, I .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1940, 62 :344-345

[6] OXIDATION CATALYSTS PRODUCED BY CATALYTIC-OXIDATION - PREPARATION, REACTIVITY AND X-RAY CRYSTAL-STRUCTURES OF [WO(O-2)(2)(PYO)(2)] AND [MOO(O-2)(2)(PYO)(2)] [J].

GRIFFITH, WP ;

SLAWIN, AMZ ;

THOMPSON, KM ;

WILLIAMS, DJ .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1994, (05) :569-570

[7] WATER-SOLUBLE METAL-COMPLEXES AND CATALYSTS .5. 2,2'-BIPYRIDINE-5-SULFONIC ACID AND ORGANOMETALLIC COMPLEXES - SPECTROSCOPY AND STRUCTURES [J].

HERRMANN, WA ;

THIEL, WR ;

KUCHLER, JG ;

BEHM, J ;

HERDTWECK, E .

CHEMISCHE BERICHTE, 1990, 123 (10) :1963-1970

[8]

JORGENSEN KA, 1989, CHEM REV, V89, P431

[9] CRUSTAL STRUCTURE OF OXODIPEROXOHEXAMETHYLPHOSPHORAMIDOAQUOMOLYBDATE(VI) AND OXODIPEROXOHEXAMETHYLPHOSPHORAMIDOPYRIDINOMOLYBDATE(VI) [J].

LECARPENTIER, JM ;

SCHLUPP, R ;

WEISS, R .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL CRYSTALLOGRAPHY AND CRYSTAL CHEMISTRY, 1972, B 28 (APR15) :1278-+

[10] HOMOGENEOUS CATALYTIC-OXIDATION OF CARBON-MONOXIDE AND KETONES WITH OXYGEN IN PRESENCE OF COMPLEXES OF RHODIUM(0), IRIDIUM(I) AND PLATINUM(0) [J].

MERCER, GD ;

BEAULIEU, WB ;

ROUNDHILL, DM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1977, 99 (20) :6551-6554