CHARACTERIZATION OF RYDBERG TRANSITIONS IN THE L2,3 ABSORPTION-SPECTRA OF SF6 AND PF5

被引：9

作者：

TSE, JS ^{[1
]}

LIU, ZF ^{[1
]}

机构：

[1] UNIV WESTERN ONTARIO, DEPT CHEM, LONDON N6A 5B7, ONTARIO, CANADA

来源：

PHYSICAL REVIEW A | 1991年 / 44卷 / 11期

关键词：

D O I：

10.1103/PhysRevA.44.7838

中图分类号：

O43 [光学];

学科分类号：

070207 ; 0803 ;

摘要：

High-resolution photoabsorption spectra of SF6 and PF5 at the L2,3 edge in the gas and solid phase have been measured with synchrotron radiation. A reduction in the intensity for some of the higher-energy transitions in the condensed phase indicates significant Rydberg character associated with the terminating orbitals. This observation is consistent with the assignments suggested by multiple-scattering X-alpha calculations and suggests that Rydberg orbitals can penetrate into the potential barrier created by the electronegative atoms.

引用

页码：7838 / 7840

页数：3

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[10]

Liu Z., UNPUB

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