DENDRIZYMES - EXPANDED LIGANDS FOR ENANTIOSELECTIVE CATALYSIS

被引：181

作者：

BRUNNER, H

机构：

[1] Institut für Anorganische Chemie, Universität Regensburg, D-93053 Regensburg

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1995年 / 500卷 / 1-2期

关键词：

DENDRIZYMES; ENANTIOSELECTIVE CATALYSIS; EXPANDED LIGANDS; TRANSITION METAL COMPLEXES;

D O I：

10.1016/0022-328X(95)00507-M

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Dendrizymes are a new class of expanded ligands, designed for enantioselective catalysis with transition metal complexes. These expanded ligands consist of a strongly binding chelate core, which is surrounded by space-filling dendrimer substituents, built-up by branching units and optically active groups. In a complex of such a dendrimer ligand a reaction is supposed to take place in the same way as in the pocket of an enzyme.

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页码：39 / 46

页数：8

相关论文

共 30 条

[1] ASYMMETRIC HYDROGENATION WITH NEW CHIRAL FUNCTIONALIZED BISPHOSPHINE-RHODIUM COMPLEXES [J].

ACHIWA, K .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1976, 98 (25) :8265-8266

[2] ASYMMETRIC CATALYSIS .88. KINETICS OF THE RH CATALYZED HYDROGENATION OF (Z)-(ALPHA)-N-ACETAMIDOCINNAMIC ACID WITH OPTICALLY-ACTIVE LAYER-PHOSPHINES AS LIGANDS [J].

BRUNNER, H ;

FURST, J ;

NAGEL, U ;

FISCHER, A .

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1994, 49 (09) :1305-1307

[3] ENANTIOSELECTIVE CATALYSIS .81. OPTICALLY-ACTIVE 2-LAYER PHOSPHINES [J].

BRUNNER, H ;

FURST, J ;

ZIEGLER, J .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1993, 454 (1-2) :87-94

[4]

BRUNNER H, 1995, SYNTHESIS-STUTTGART, P423

[5] ENANTIOSELECTIVE CATALYSIS .85. OPTICALLY-ACTIVE EXPANDED CHELATE PHOSPHINES DERIVED FROM 1,OMEGA-BIS(DICHLOROPHOSPHINO)ALKANES [J].

BRUNNER, H ;

FURST, J .

TETRAHEDRON, 1994, 50 (15) :4303-4310

[6]

BRUNNER H, 1995, SYNTHESIS-STUTTGART, P36

[7] ENANTIOSELECTIVE CATALYSIS, .90. OPTICALLY-ACTIVE NITROGEN LIGANDS WITH DENDRIMERIC STRUCTURE [J].

BRUNNER, H ;

ALTMANN, S .

CHEMISCHE BERICHTE, 1994, 127 (11) :2285-2296

[8] ASYMMETRIC HYDROGENATION OF (Z)-ALPHA-(ACETYLAMINO)-CINNAMIC ACID BY A RH-NORPHOS CATALYST [J].

BRUNNER, H ;

PIERONCZYK, W .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1979, 18 (08) :620-621

[9] ASYMMETRIC CATALYZES .5. ENANTIOSELECTIVE AMINO-ACID SYNTHESIS BY HYDROGENATION OF PROCHIRAL OLEFINS WITH RH-COMPLEXES OF THE NEW OPTICALLY-ACTIVE CHELATING PHOSPHANE NORPHOS [J].

BRUNNER, H ;

PIERONCZYK, W ;

SCHONHAMMER, B ;

STRENG, K ;

BERNAL, I ;

KORP, J .

CHEMISCHE BERICHTE-RECUEIL, 1981, 114 (03) :1137-1149

[10]

Brunner H., 1979, ANGEW CHEM, V91, P655