SYNTHESIS AND STRUCTURE OF THE NOVEL GA3P3 RING COMPOUND [(2,4,6-PH3C6H2)GAP(CYCLO-C6H11)]3

被引：40

作者：

HOPE, H

PESTANA, DC

POWER, PP

机构：

[1] Department of Chemistry, University of California, Davis, California

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1991年 / 30卷 / 06期

关键词：

D O I：

10.1002/anie.199106911

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The central ring system in 1 consists exclusively of three-coordinate heavy main group elements. In contrast to its B-P analogue the Ga3P3 ring is not planar, i.e. pi-pi overlap with formation of a cyclic delocalized electron system is not favored. Nevertheless, it contains the hitherto shortest Ga-P bond (mean length 2.3 angstrom).

引用

页码：691 / 693

页数：3