VIBRATIONAL PREDISSOCIATIVE LIFETIMES OF (10(0)0) AR...HCL AND (10(0)0) KR...HCL FROM TIME-OF-FLIGHT MEASUREMENTS IN A PULSED-NOZZLE, FT MICROWAVE SPECTROMETER

被引：7

作者：

BEVAN, JW

LEGON, AC

REGO, CA

机构：

[1] Department of Chemistry, University of Exeter, Exeter, EX4 4QD, Stocker Road

来源：

CHEMICAL PHYSICS LETTERS | 1993年 / 204卷 / 5-6期

关键词：

D O I：

10.1016/0009-2614(93)89202-S

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The variation with time-of-flight t of the population N1 of the vibrational state (10(0)0) in Rg ... HCl (Rg = Ar and Kr) has been measured in a pulsed-nozzle, Fourier-transform microwave spectrometer. Excited-state molecules were produced with a pulsed, dc glow-discharge nozzle. N1 was found to be independent of t in the range 0-300 mus for Ar ... HCl and 0 to 400 mus for Kr ... HCl. The vibrational predissociative lifetime tau(vp) greater than or similar to 1 ms is estimated for each of these (10(0)0) state Rg ... HCl molecules.

引用

页码：551 / 555

页数：5

共 11 条

[1]

[Anonymous], 1922, T FARADAY SOC, DOI DOI 10.1039/TF9221700598

[2] VIBRATION-ROTATIONAL EINSTEIN COEFFICIENTS FOR HF DF AND HCI DCI [J].