ENHANCED DECARBAMOYLATION OF D(-)-N-CARBAMOYL PHENYL GLYCINE BY ITS INTERFACIAL SOLUBILIZATION UNDER MICELLAR CONDITIONS

被引：5

作者：

JHA, BK

CHHATRE, AS

KULKARNI, BD

JOSHI, RA

JOSHI, RR

KALKOTE, UR

机构：

[1] NATL CHEM LAB,DIV CHEM ENGN,POONA 411008,MAHARASHTRA,INDIA

[2] NATL CHEM LAB,DIV ORGAN CHEM TECHNOL,POONA 411008,MAHARASHTRA,INDIA

来源：

JOURNAL OF COLLOID AND INTERFACE SCIENCE | 1994年 / 163卷 / 01期

关键词：

D O I：

10.1006/jcis.1994.1074

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

D(-)-N-carbamoyl phenyl glycine is solubilized in the micellar/microemulsion solution of dilute sulfuric acid using sodium dodecyl sulfate (SDS) as surfactant and treated with sodium nitrite (limiting component) to produce quantitative yield of D(-)-phenyl glycine, an important drug intermediate. The solubilization, phase behavior, and reaction product distributions are analyzed to explain the interfacial phenomena involved. © 1994 by Academic Press, Inc.

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页码：1 / 9

页数：9

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