THE DIASTEREOSELECTIVITY OF THE ADDITION OF TRICARBONYL(ETA(6)-2-LITHIOTHIOPHENE)CHROMIUM(0) COMPLEXES ON ALDEHYDES

被引：7

作者：

STRUHARIK, M ^{[1
]}

TOMA, S ^{[1
]}

机构：

[1] COMENIUS UNIV BRATISLAVA,FAC SCI,DEPT ORGAN CHEM,CS-84215 BRATISLAVA,SLOVAKIA

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1994年 / 464卷 / 01期

关键词：

CHROMIUM; THIOPHENE; CARBONYL; ALDEHYDE;

D O I：

10.1016/0022-328X(94)87009-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

It has been shown that the reactions of tricarbonyl(eta(6)-2-lithiothiophene)chromium(0) with various arene carboxaldehydes yields mixtures of unequal amounts of diastereoisomers, which can be separated by flash chromatography. The structures of the products have been established by H-1 NMR spectroscopy and by independent synthesis. A novel synthesis of tricarbonyl(eta(6)-thiophene)-chromium(0) (1) is described. (I) is described.

引用

页码：59 / 63

页数：5

共 17 条

[1] DIASTEREOSELECTIVE COMPLEXATION OF BENZYLIC ALCOHOLS BY HEXACARBONYL CHROME - DIFFERENCE OF DIASTEREOISOMER REACTIVITY IN ACIDIC MEDIA [J].

BROCARD, J ;

LEBIBI, J ;

PELINSKI, L ;

MAHMOUDI, M .

TETRAHEDRON LETTERS, 1986, 27 (52) :6325-6328

[2] STEREOSELECTIVE SYNTHESIS OF ARENECHROMIUM TRICARBONYL COMPLEXES - ORIGINS OF THE BENZYLIC OXYGEN DIRECTING EFFECTS FOR 1-TETRALOL DERIVATIVES [J].

DAVIES, SG ;

GOODFELLOW, CL .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1988, 340 (02) :195-201

[3] TRICARBONYLPYRIDINECHROMIUM COMPLEXES - STEREOSELECTIVE ALKYLATIONS AND ALDOL-TYPE REACTIONS INVOLVING ALPHA-CARBANIONS DERIVED FROM ETA-TRICARBONYL(2-ALKYL-PYRIDINE)CHROMIUM COMPLEXES [J].

DAVIES, SG ;

EDWARDS, AJ ;

SHIPTON, MR .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1991, (05) :1009-1017

[4] ETA-6-BENZENETRICARBONYLCHROMIUM ANALOGS OF CHALCONES [J].

FEDERIC, J ;

TOMA, S ;

GAUTHERON, B .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1988, 338 (02) :211-216

[5] UBER AROMATENKOMPLEXE VON METALLEN .22. THIOPHEN-CHROM(0)-TRICARBONYL [J].

FISCHER, EO ;

OFELE, K .

CHEMISCHE BERICHTE-RECUEIL, 1958, 91 (11) :2395-2399

[6] THE STUDY OF CATALYST EFFECTS ON THE COMPLEXATION OF ARENES WITH CR(CO)6 - AN OVERVIEW [J].

HUDECEK, M ;

GAJDA, V ;

TOMA, S .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1991, 413 (1-3) :155-160

[7] NAPHTHALENE COMPLEXES .5. ARENE EXCHANGE-REACTIONS IN NAPHTHALENECHROMIUM COMPLEXES [J].

KUNDIG, EP ;

PERRET, C ;

SPICHIGER, S ;

BERNARDINELLI, G .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1985, 286 (02) :183-200

[8]

KUNDIG EP, 1991, SYNLETT, P657

[9]

MANGINI A, 1968, INORG CHIM ACTA, V2, P12

[10] RING METALATION OF THIOPHENECHROMIUM TRICARBONYL WITH BUTYLLITHIUM [J].

NEFEDOVA, MN ;

SETKINA, VN ;

KURSANOV, DN .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1983, 244 (02) :C21-C23

← 1 2 →