XPS STUDIES OF GAMMA-AL2O3-SUPPORTED MOLYBDENUM COMPLEXES

被引：8

作者：

KLIMOV, OV ^{[1
]}

KRIVOSHCHEKOVA, EA ^{[1
]}

KALINKIN, AV ^{[1
]}

STARTSEV, AN ^{[1
]}

机构：

[1] NOVOSIBIRSK CATALYSIS INST,NOVOSIBIRSK 630090,USSR

来源：

REACTION KINETICS AND CATALYSIS LETTERS | 1991年 / 43卷 / 02期

关键词：

D O I：

10.1007/BF02064689

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

XPS studies of molybedenum state in individual and Al2O3-supported complexes MoO2 (C5H7O2)2, (N2H5)2[MoO4(C2O4)2(H2O)2], (N2H5)2 [Mo2O 4(OH) 4 (H2O)2] and (NH4) 2 [Mo3O4 (C2O4)3 (H2O)3] showed that when its oxidation state changes by unity, BE Mo 3d5/2 in individual complexes changes by about 1 eV, whereas in surface compounds its change equals about approximately 0.6 eV.

引用

页码：301 / 305

页数：5

共 13 条

[11] INTERACTION OF TRANSITION-METAL ACETYLACETONATES WITH GAMMA-AL2O3 SURFACES [J].