AN UNPRECEDENTED CHEMICAL TRANSFORMATION - THE OXIDATION OF ALKANES TO ALKYL DIMETHYL PHOSPHATES

被引:15
作者
BARTON, DHR
BEVIERE, SD
DOLLER, D
机构
[1] Department of Chemistry, Texas A and M University, College Station
关键词
D O I
10.1016/S0040-4039(00)92278-0
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Treatment of alkanes under Gif(IV) conditions [FeCl2.4H2O (cat.), Zn0, and O2 in pyridine-acetic acid] in the presence of trimethylphosphite afforded alkyl dimethyl phosphates; C-13-NMR experiments showed that the phosphates are formed from the reaction between the intermediate alkyl hydroperoxide and trimethyl phosphite in the presence of an iron catalyst.
引用
收藏
页码:4671 / 4674
页数:4
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