AN UNPRECEDENTED CHEMICAL TRANSFORMATION - THE OXIDATION OF ALKANES TO ALKYL DIMETHYL PHOSPHATES

被引：15

作者：

BARTON, DHR

BEVIERE, SD

DOLLER, D

机构：

[1] Department of Chemistry, Texas A and M University, College Station

来源：

TETRAHEDRON LETTERS | 1991年 / 32卷 / 36期

关键词：

D O I：

10.1016/S0040-4039(00)92278-0

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Treatment of alkanes under Gif(IV) conditions [FeCl2.4H2O (cat.), Zn0, and O2 in pyridine-acetic acid] in the presence of trimethylphosphite afforded alkyl dimethyl phosphates; C-13-NMR experiments showed that the phosphates are formed from the reaction between the intermediate alkyl hydroperoxide and trimethyl phosphite in the presence of an iron catalyst.

引用

页码：4671 / 4674

页数：4

共 13 条

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