DIVERSE ORIGINS OF FLUID IN MAGMATIC INCLUSIONS AT BINGHAM (UTAH, USA), BUTTE (MONTANA, USA), ST-AUSTELL (CORNWALL, UK), AND ASCENSION-ISLAND (MID-ATLANTIC, UK), INDICATED BY LASER MICROPROBE ANALYSIS OF CL, K, BR, I, BA PLUS TE, U, AR, KR, AND XE

被引:69
作者
IRWIN, JJ [1 ]
ROEDDER, E [1 ]
机构
[1] HARVARD UNIV,DEPT EARTH & PLANETARY SCI,CAMBRIDGE,MA 02138
基金
美国国家科学基金会;
关键词
D O I
10.1016/0016-7037(94)00285-T
中图分类号
P3 [地球物理学]; P59 [地球化学];
学科分类号
0708 ; 070902 ;
摘要
Saline fluid inclusions (FI) trapped at close to the temperature of final solidification of a granitic melt occur in rocks from Bingham, Utah, Ascension Island, mid-Atlantic Ocean, and St. Austell, Cornwall. Slightly lower temperature FI occur at Butte, Montana. Argon, Kr, and Xe were extracted from FI by laser microprobe decrepitation of minute portions of the samples after neutron irradiation (along with synthetic FI of known composition), and measured in a low blank, high sensitivity, pulse-counting mass spectrometer. Results enable measurement of Cl, K, Br, and I simultaneously with Ar-36, Ar-40, Kr-84, and Xe-129, in approximately 10(-7) cc of fluid, the contents of a single spherical inclusion approximately 57 mum in diameter. Average K/Cl in Bingham and St. Austell FI are approximately 0.25 and approximately 0.15, respectively, broadly consistent with the composition of fluids equilibrated with rocks at temperatures close to the eutectic in the granite system (400-600-degrees-C and 0.5-2 Kb). Within-sample variations in K/Cl are significant and may be a result of exsolution of fluids from magmas over a range of temperatures and/or pressures. Halogen ratios are confined to a narrow range, with I/Cl and Br/Cl in Bingham, Ascension, and some Butte FI approximately 1 - 8 x 10(-5) and 1 - 3 x 10(-3), respectively, probably evidence of a common source of salinity, presumably part of the Earth's mantle. A component of salinity derived from continental crust may be indicated by higher I/Cl and lower Br/Cl in St. Austell FI. Radiogenic Ar-40 produced in situ from K in FI after trapping is usually insignificant. Ar-40e is defined as Ar-40 in excess of the amounts attributable to atmospheric gases and that produced by decay of K in FI. Variations in Ar-40e/Cl in Bingham, Ascension, and St. Austell FI are greater than can be explained by just different Cl concentrations in FI, (typically between approximately 5 x 10(-7) and 8 x 10(-6)), probably because Ar and Cl have been fractionated within these systems by outgassing of a magma in the interval between exsolution of different FI generations. Concentrations of Ar and Kr-84 in most Bingham, Ascension, and St. Austell FI are approximately 2 orders of magnitude greater than in most lavas and granites, with Kr-84/Ar-36 ranging between approximately 0.015 and approximately 0.08, grossly consistent with the composition of fluids exsolved from magmas. Several distinct fluid types are present at Butte: (1) rare ''magmatic'' FI having halogen and noble gas abundances similar to Bingham and Ascension and (2) abundant FI having Ar-36 and Kr-84 concentrations similar to air-saturated fresh waters, with slightly lower Br/Cl than FI at Bingham and Ascension (approximately 5 - 10 x 10(-4)) and relatively high Ar-40e/Cl (approximately 1 x 10(-5) and 2.8 x 10(-5). Mixing prior to trapping between fluid derived from magmas and meteoric water that acquired Ar-40e plus some halogens by interaction with country rocks is the most likely origin of most Butte FI.
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页码:295 / 312
页数:18
相关论文
共 115 条
[11]   LASER MICROPROBE ANALYSES OF NOBLE-GAS ISOTOPES AND HALOGENS IN FLUID INCLUSIONS - ANALYSES OF MICROSTANDARDS AND SYNTHETIC INCLUSIONS IN QUARTZ [J].
BOHLKE, JK ;
IRWIN, JJ .
GEOCHIMICA ET COSMOCHIMICA ACTA, 1992, 56 (01) :187-201
[12]  
BOHLKE JK, 1989, US GEOL SURVEY B, V1890, P61
[13]   CL, BR AND I ANALYSES OF METAMORPHIC AND SEDIMENTARY-ROCKS BY ISOTOPE-DILUTION MASS-SPECTROMETRY [J].
BONESS, M ;
HEUMANN, KG ;
HAACK, U .
CONTRIBUTIONS TO MINERALOGY AND PETROLOGY, 1991, 107 (01) :94-99
[14]   THE COMPOSITION OF A PRIMARY GRANITE-DERIVED ORE FLUID FROM SW ENGLAND, DETERMINED BY FLUID INCLUSION ANALYSIS [J].
BOTTRELL, SH ;
YARDLEY, BWD .
GEOCHIMICA ET COSMOCHIMICA ACTA, 1988, 52 (02) :585-588
[15]   CHEMICAL AND ISOTOPIC EVOLUTION OF HYDROTHERMAL SOLUTIONS AT BINGHAM, UTAH [J].
BOWMAN, JR ;
PARRY, WT ;
KROPP, WP ;
KRUER, SA .
ECONOMIC GEOLOGY, 1987, 82 (02) :395-428
[16]   ORIGIN AND ORE-FORMING CONSEQUENCES OF THE ADVANCED ARGILLIC ALTERATION PROCESS IN HYPOGENE ENVIRONMENTS BY MAGMATIC GAS CONTAMINATION OF METEORIC FLUIDS [J].
BRIMHALL, GH ;
GHIORSO, MS .
ECONOMIC GEOLOGY, 1983, 78 (01) :73-90
[17]   ARGON AND HALOGEN GEOCHEMISTRY OF HYDROTHERMAL FLUIDS IN THE LOCH-AINORT GRANITE, ISLE-OF-SKYE, SCOTLAND [J].
BURGESS, R ;
PARSONS, I .
CONTRIBUTIONS TO MINERALOGY AND PETROLOGY, 1994, 115 (03) :345-355
[18]  
BURGESS R, 1993, EOS T AM GEOPHYS UN, V74, P636
[19]  
Burnham C.W., 1979, GEOCHEMISTRY HYDROTH, P71
[20]  
Candela P.A., 1989, REV EC GEOLOGY, V4, P203