ANALYSIS OF CHIRAL CARBOXYLIC-ACIDS BY NMR USING NEW OPTICALLY-ACTIVE AMINES

被引：21

作者：

KUHN, M ^{[1
]}

BUDDRUS, J ^{[1
]}

机构：

[1] INST SPEKTROCHEM & ANGEW SPEKT,POSTFACH 101352,W-4600 DORTMUND 1,GERMANY

来源：

TETRAHEDRON-ASYMMETRY | 1993年 / 4卷 / 02期

关键词：

D O I：

10.1016/S0957-4166(00)82339-3

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The two amines (+)-9-(1-aminoethyl)phenanthrene 3 and (-)-9-(1-amino-ethyl)anthracene 4 have been prepared by resolution of the corresponding racemic amines and tested as auxiliaries for the NMR analysis of racemic carboxylic acids including highly polar acids such as 6. (-)-4 turns out to be the most effective auxiliary among the arylmethylamines of type 1.

引用

页码：207 / 210

页数：4

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