2ND-ROW AND 3RD-ROW TRANSITION-METAL COMPLEXES OF DIHYDROXYBENZOIC ACIDS, AND THE CRYSTAL-STRUCTURE OF [NME(4)](2)[MOO2(2,3-DHB)(2)]CENTER-DOT-1.5H(2)O(2,3-H(2)DHB=2,3-DIHYDROXYBENZOIC ACID)

被引：57

作者：

GRIFFITH, WP

NOGUEIRA, HIS

PARKIN, BC

SHEPPARD, RN

WHITE, AJP

WILLIAMS, DJ

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1995年 / 11期

关键词：

D O I：

10.1039/dt9950001775

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The new complexes [MO(2)L(2)](2-) (H(2)L = 2,3- or 3,4-dihydroxybenzoic acid. 2,3-H(2)dhb or 3,4-H(2)dhb, M = Mo, W or Os; H(2)L = 2.6-dihydroxybenzoic acid, 2,6-H(2)dhb, M = Mo), [OsO2(py)(2)(2,6-dhb)] (Py = Pyridine), [ReO\(PPh(3))(2)L] (H(2)L = 2,3-, 3,4- or 2,6-H(2)dhb) and [M(PPh(3))(2)(2,3-dhb)] (M = Pd or Pt) have been prepared. The crystal structure of [NMe(4)](2)[MoO2(2,3-dhb)(2)]. 1.5H(2)O has been determined and exhibits catecholato rather than salicylato type bonding. Infrared. Raman,H-1 and C-13- (H-1) NM R spectroscopic data for the complexes are also presented.

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页码：1775 / 1781

页数：7

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