SYNTHESES AND INTERCONVERSION OF [BIS(SILYL)ALKENE]PALLADIUM(0) AND BIS(SILYL)PALLADIUM(II) COMPLEXES - A MECHANISTIC MODEL FOR PALLADIUM-CATALYZED BIS-SILYLATION

被引：72

作者：

MURAKAMI, M

YOSHIDA, T

ITO, Y

机构：

[1] Department of Synthetic Chemistry, Faculty of Engineering, Kyoto University, Yoshida

来源：

ORGANOMETALLICS | 1994年 / 13卷 / 07期

关键词：

D O I：

10.1021/om00019a055

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two palladium complexes, [bis(trialkylsilyl)-alkene]palladium(0) and bis(trialkylsilyl)palladium(II), have been synthesized and structurally determined. The interconversion of these palladium complexes supports the postulated mechanism of palladium-catalyzed bis-silylation of C-C triple bonds.

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页码：2900 / 2902

页数：3

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