CATALYTIC C-H ACTIVATION BY RHCL(CO)(PME3)2-H-NU SYSTEM

被引：44

作者：

TANAKA, M

SAKAKURA, T

机构：

[1] National Chemical Laboratory for Industry, Higashi, Tsukuba

来源：

PURE AND APPLIED CHEMISTRY | 1990年 / 62卷 / 06期

关键词：

D O I：

10.1351/pac199062061147

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

RhC1(C0)(PMe3)2 under irradiation is a powerful catalyst which can functionalize hydrocarbons including alkanes under mild conditions. The reaction with carbon monoxide leads to the formation of the corresponding aldehyde. Alkanes react regioselectively at the terminal methyl group. The reaction of alkanes under inert atmosphere results in the formation of alkenes with a concomitant evolution of dihydrogen. Terminal alkene is obtained from n-alkane in the presence of excess amount of PMe3 ligand. The irradiation is essential to cause the catalytic C-H activation. © 1990 IUPAC

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页码：1147 / 1150

页数：4

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