GREEN LUMINESCENCE FROM COPPER-DOPED ZINC-SULFIDE QUANTUM PARTICLES

被引:262
作者
KHOSRAVI, AA
KUNDU, M
JATWA, L
DESHPANDE, SK
BHAGWAT, UA
SASTRY, M
KULKARNI, SK
机构
[1] NMV COLL,DEPT CHEM,POONA 411030,MAHARASHTRA,INDIA
[2] NATL CHEM LAB,POONA 411008,MAHARASHTRA,INDIA
关键词
D O I
10.1063/1.114298
中图分类号
O59 [应用物理学];
学科分类号
摘要
Free-standing powder of zinc sulphide quantum particles has been synthesized using a chemical route. X-ray diffraction analysis shows that the diameter of the particles is similar to 21+/-2 Angstrom which is smaller than the Bohr exciton diameter for zinc sulphide. UV absorption shows an excitonic peak centered at similar to 300 nm corresponding to an energy gap of 4.1+/-0.1 eV. These particles show a luminescence band at similar to 424 nm. The quantum particles could be doped with copper during synthesis without altering the UV absorption or x-ray diffraction pattern. However, doping shifted the luminescence to 480 nm, green wavelength in the visible region. (C) 1995 American Institute of Physics.
引用
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页码:2702 / 2704
页数:3
相关论文
共 18 条
[1]   PHOTOCHEMISTRY AND RADIATION-CHEMISTRY OF COLLOIDAL SEMICONDUCTORS .12. INTERMEDIATES OF THE OXIDATION OF EXTREMELY SMALL PARTICLES OF CDS, ZNS, AND CD3P2 AND SIZE QUANTIZATION EFFECTS (A PULSE-RADIOLYSIS STUDY) [J].
BARAL, S ;
FOJTIK, A ;
WELLER, H ;
HENGLEIN, A .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1986, 108 (03) :375-378
[2]   OPTICAL-PROPERTIES OF MANGANESE-DOPED NANOCRYSTALS OF ZNS [J].
BHARGAVA, RN ;
GALLAGHER, D ;
HONG, X ;
NURMIKKO, A .
PHYSICAL REVIEW LETTERS, 1994, 72 (03) :416-419
[3]   ELECTRONIC STRUCTURE OF CENTERS IN ZNS [J].
BIRMAN, JL .
PHYSICAL REVIEW, 1961, 121 (01) :144-&
[5]   THE COPPER CENTER - A TRANSIENT SHALLOW ACCEPTOR IN ZNS AND CDS [J].
HEITZ, R ;
HOFFMANN, A ;
THURIAN, P ;
BROSER, I .
JOURNAL OF PHYSICS-CONDENSED MATTER, 1992, 4 (01) :157-168
[6]   NUCLEATION AND GROWTH OF CDSE ON ZNS QUANTUM CRYSTALLITE SEEDS, AND VICE VERSA, IN INVERSE MICELLE MEDIA [J].
KORTAN, AR ;
HULL, R ;
OPILA, RL ;
BAWENDI, MG ;
STEIGERWALD, ML ;
CARROLL, PJ ;
BRUS, LE .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (04) :1327-1332
[7]   INTEGRATED CHEMICAL-SYSTEMS - PHOTOCATALYSIS AT SEMICONDUCTORS INCORPORATED INTO POLYMER (NAFION) MEDIATOR SYSTEMS [J].
KRISHNAN, M ;
WHITE, JR ;
FOX, MA ;
BARD, AJ .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1983, 105 (23) :7002-7003
[8]  
ORTIZ A, 1989, J ELECTROCHEM SOC, V136, P1282
[9]   EMPIRICAL ONE-ELECTRON MODEL OF OPTICAL-TRANSITIONS IN CU-DOPED ZNS AND CDS [J].
PEKA, P ;
SCHULZ, HJ .
PHYSICA B, 1994, 193 (01) :57-65
[10]   EXCITED ELECTRONIC STATES AND OPTICAL-SPECTRA OF ZNS AND CDS CRYSTALLITES IN THE ALMOST-EQUAL-TO-15 TO 50-A SIZE RANGE - EVOLUTION FROM MOLECULAR TO BULK SEMICONDUCTING PROPERTIES [J].
ROSSETTI, R ;
HULL, R ;
GIBSON, JM ;
BRUS, LE .
JOURNAL OF CHEMICAL PHYSICS, 1985, 82 (01) :552-559