THE DRIVING-FORCE DEPENDENCE OF ELECTROCHEMICAL RATE PARAMETERS - ORIGINS OF ANODIC-CATHODIC ASYMMETRIES FOR METAL-AQUO REDOX COUPLES

被引：50

作者：

HUPP, JT ^{[1
]}

WEAVER, MJ ^{[1
]}

机构：

[1] PURDUE UNIV, DEPT CHEM, W LAFAYETTE, IN 47907 USA

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1984年 / 88卷 / 25期

关键词：

D O I：

10.1021/j150669a015

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

引用

页码：6128 / 6135

页数：8

共 50 条

[1] THE NONADIABATICITY PROBLEM OF OUTER-SPHERE ELECTRON-TRANSFER REACTIONS - REDUCTION AND OXIDATION OF EUROPIUM IONS [J].

BALZANI, V ;

SCANDOLA, F ;

ORLANDI, G ;

SABBATINI, N ;

INDELLI, MT .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1981, 103 (12) :3370-3378

[2]

BEST SP, J CHEM SOC DA

[3]

BOCKRIS JO, 1970, MODERN ELECTROCHEMIS, V1, pCH2

[4]

BOCKRIS JO, 1979, QUANTUM ELECTROCHEMI, pCH7

[5] KINETICS OF OXIDATION OF FE(H2O)62+ BY POLYPYRIDINE COMPLEXES OF RUTHENIUM(III) - NEGATIVE ENTHALPIES OF ACTIVATION [J].

BRADDOCK, JN ;

MEYER, TJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1973, 95 (10) :3158-3162

[6] COMPARISON OF THE RATES OF ELECTRON EXCHANGE-REACTIONS OF AMMINE COMPLEXES OF RUTHENIUM(II) AND RUTHENIUM(III) WITH THE PREDICTIONS OF ADIABATIC, OUTER-SPHERE ELECTRON-TRANSFER MODELS [J].

BROWN, GM ;

SUTIN, N .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1979, 101 (04) :883-892

[7] THE ROLE OF INNER-SPHERE CONFIGURATION CHANGES IN ELECTRON-EXCHANGE REACTIONS OF METAL-COMPLEXES [J].

BRUNSCHWIG, BS ;

CREUTZ, C ;

MACARTNEY, DH ;

SHAM, TK ;

SUTIN, N .

FARADAY DISCUSSIONS, 1982, 74 :113-127

[8] RATE CONSTANTS AND ACTIVATION PARAMETERS FOR OUTER-SPHERE ELECTRON-TRANSFER REACTIONS AND COMPARISONS WITH PREDICTIONS OF MARCUS THEORY [J].

CHOU, M ;

CREUTZ, C ;

SUTIN, N .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1977, 99 (17) :5615-5623

[9] CYCLIC VOLTAMMETRIC STUDY OF TERT-NITROBUTANE REDUCTION IN ACETONITRILE AT MERCURY AND PLATINUM-ELECTRODES - OBSERVATION OF A POTENTIAL DEPENDENT ELECTROCHEMICAL TRANSFER-COEFFICIENT AND THE INFLUENCE OF THE ELECTROLYTE CATION ON THE RATE-CONSTANT [J].

CORRIGAN, DA ;

EVANS, DH .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1980, 106 (1-2) :287-304

[10] UNUSUAL ACTIVATION PARAMETERS IN OXIDATION OF FE(H2O)62+ BY POLYPYRIDINE COMPLEXES OF IRON(III) - EVIDENCE FOR MULTIPLE PATHS FOR OUTER-SPHERE ELECTRON-TRANSFER [J].

CRAMER, JL ;

MEYER, TJ .

INORGANIC CHEMISTRY, 1974, 13 (05) :1250-1252

← 1 2 3 4 5 →