THE DRIVING-FORCE DEPENDENCE OF ELECTROCHEMICAL RATE PARAMETERS - ORIGINS OF ANODIC-CATHODIC ASYMMETRIES FOR METAL-AQUO REDOX COUPLES

被引：50

作者：

HUPP, JT ^{[1
]}

WEAVER, MJ ^{[1
]}

机构：

[1] PURDUE UNIV, DEPT CHEM, W LAFAYETTE, IN 47907 USA

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1984年 / 88卷 / 25期

关键词：

D O I：

10.1021/j150669a015

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

引用

页码：6128 / 6135

页数：8

共 50 条

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[13] EXAMINATION OF THE INTRINSIC BARRIER TO ELECTRON-TRANSFER IN HEXAAQUOCOBALT(III) - EVIDENCE FOR VERY SLOW OUTER-SPHERE SELF-EXCHANGE RESULTING FROM CONTRIBUTIONS OF FRANCK-CONDON AND ELECTRONIC TERMS [J].

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[14] UNIFIED VIEW OF MARCUS ELECTRON-TRANSFER AND MULLIKEN CHARGE-TRANSFER THEORIES IN ORGANOMETALLIC CHEMISTRY - STERIC EFFECTS IN ALKYLMETALS AS QUANTITATIVE PROBES FOR OUTER-SPHERE AND INNER-SPHERE MECHANISMS [J].

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[15] POTENTIAL DEPENDENCE OF THE ELECTROCHEMICAL TRANSFER-COEFFICIENT - IMPEDANCE STUDY OF THE REDUCTION OF AROMATIC-COMPOUNDS [J].

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JOURNAL OF PHYSICAL CHEMISTRY, 1979, 83 (23) :3003-3007

[16] INFLUENCE OF SPECIFIC REACTANT SOLVENT INTERACTIONS ON INTRINSIC ACTIVATION ENTROPIES FOR OUTER-SPHERE ELECTRON-TRANSFER REACTIONS [J].

HUPP, JT ;

WEAVER, MJ .

JOURNAL OF PHYSICAL CHEMISTRY, 1984, 88 (09) :1860-1864

[17] ELECTROCHEMICAL AND HOMOGENEOUS EXCHANGE KINETICS FOR TRANSITION-METAL AQUO COUPLES - ANOMALOUS BEHAVIOR OF HEXAAQUOIRON(III/II) [J].

HUPP, JT ;

WEAVER, MJ .

INORGANIC CHEMISTRY, 1983, 22 (18) :2557-2564

[18] THE FREQUENCY FACTOR FOR OUTER-SPHERE ELECTROCHEMICAL REACTIONS [J].

HUPP, JT ;

WEAVER, MJ .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1983, 152 (1-2) :1-14

[19] EXPERIMENTAL ESTIMATE OF THE ELECTRON-TUNNELING DISTANCE FOR SOME OUTER-SPHERE ELECTROCHEMICAL REACTIONS [J].

HUPP, JT ;

WEAVER, MJ .

JOURNAL OF PHYSICAL CHEMISTRY, 1984, 88 (08) :1463-1467

[20]

HUPP JT, UNPUB

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