A D4-THIOLATO DINITROGEN COMPLEX - THE SYNTHESIS AND CRYSTAL-STRUCTURE OF [RE(N2)(SC6H2-2,4,6-PRI3)3(PPH3)]

被引：28

作者：

DILWORTH, JR ^{[1
]}

HU, J ^{[1
]}

THOMPSON, RM ^{[1
]}

HUGHES, DL ^{[1
]}

机构：

[1] UNIV SUSSEX,AFRC,IPSR NITROGEN FIXAT LAB,BRIGHTON BN1 9RQ,E SUSSEX,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 07期

关键词：

D O I：

10.1039/c39920000551

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

[ReH7(PPh3)2] or [ReH5(PPh3)3] reacted with L[L = 2,4,6-triisopropylthiophenol (Htipt) or HSC6H2-2,6-Pri2,4-Br (Hdipbt)] in toluene, under dinitrogen, to give [Re(N2)(tipt)3(PPh3)] and [Re(N2)(dipbt)3(PPh3)], respectively in good yield, and under similar conditions 2,6-dimethylthiophenol (Hdmt) or 2,6-dimethoxythiophenol (Hdmot) gave [Re(dmt)3(PPh3)] and [Re(dmot)3(PPh3)] respectively; the complex [Re(dmt)3(PPh3)(PPh2H)] was also isolated from the same reaction with Hdmt.

引用

页码：551 / 553

页数：3

共 21 条

[1] REACTION OF (PPH3)2REH7 WITH DIENES - PREPARATION AND SOME PROPERTIES OF TRIHYDRIDO ETA-4-DIENE COMPLEXES OF RHENIUM [J].

BAUDRY, D ;

EPHRITIKHINE, M ;

FELKIN, H .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1982, 224 (04) :363-376

[2] COMPLEXES OF MOLYBDENUM WITH STERICALLY HINDERED THIOLATO-LIGANDS [J].

BISHOP, PT ;

BLOWER, PJ ;

DILWORTH, JR ;

ZUBIETA, JA .

POLYHEDRON, 1986, 5 (1-2) :363-367

[3] RHENIUM NITROSYL COMPLEXES WITH SIMPLE AND WITH STERICALLY DEMANDING AROMATIC THIOLATE LIGANDS - X-RAY CRYSTAL-STRUCTURES OF [PPH4][RE2(SC6H4-ME-4)7(NO)2].CH2CL2 AND [RE(SC6H3PRI2-2,6)4(NO)] [J].

BLOWER, PJ ;

DILWORTH, JR ;

HUTCHINSON, JP ;

ZUBIETA, JA .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1985, (08) :1533-1541

[4] THE EFFECTS OF STERIC HINDRANCE ON THE CHEMISTRY OF RHENIUM AND MOLYBDENUM NITROSYL THIOLATO-COMPLEXES - THE STRUCTURES OF [MO(SC6H2PR3I)3(NH3)(NO)] AND [RE(SC6H3PR2I)4(NO)] [J].

BLOWER, PJ ;

BISHOP, PT ;

DILWORTH, JR ;

HSIEH, TC ;

HUTCHINSON, J ;

NICHOLSON, T ;

ZUBIETA, J .

INORGANICA CHIMICA ACTA-ARTICLES AND LETTERS, 1985, 101 (01) :63-65

[5]

BLOWER PJ, 1985, J CHEM SOC DA, P2035

[6] MONOHYDRIDE COMPLEXES OF MOLYBDENUM(IV) AND TUNGSTEN(IV) CONTAINING BULKY THIOLATE LIGANDS - X-RAY CRYSTAL-STRUCTURES OF [MH(SC6H2PRI3-2,4,6)3(PME2PH)2], M = MO OR W [J].

BURROW, TE ;

HILLS, A ;

HUGHES, DL ;

LANE, JD ;

MORRIS, RH ;

RICHARDS, RL .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1991, (07) :1813-1820

[7]

CHATT J, 1974, J CHEM SOC DALTON, P2358, DOI 10.1039/dt9740002358

[8] HYDRIDO-COMPLEXES OF RHENIUM-CONTAINING TERTIARY PHOSPHINES [J].

CHATT, J ;

COFFEY, RS .

JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1969, (13) :1963-&

[9]

CHATT J, 1973, J CHEM SOC DA, P613

[10] H-H, C-H, AND RELATED SIGMA-BONDED GROUPS AS LIGANDS [J].

CRABTREE, RH ;

HAMILTON, DG .

ADVANCES IN ORGANOMETALLIC CHEMISTRY, 1988, 28 :299-338

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