A D4-THIOLATO DINITROGEN COMPLEX - THE SYNTHESIS AND CRYSTAL-STRUCTURE OF [RE(N2)(SC6H2-2,4,6-PRI3)3(PPH3)]

被引：28

作者：

DILWORTH, JR ^{[1
]}

HU, J ^{[1
]}

THOMPSON, RM ^{[1
]}

HUGHES, DL ^{[1
]}

机构：

[1] UNIV SUSSEX,AFRC,IPSR NITROGEN FIXAT LAB,BRIGHTON BN1 9RQ,E SUSSEX,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 07期

关键词：

D O I：

10.1039/c39920000551

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

[ReH7(PPh3)2] or [ReH5(PPh3)3] reacted with L[L = 2,4,6-triisopropylthiophenol (Htipt) or HSC6H2-2,6-Pri2,4-Br (Hdipbt)] in toluene, under dinitrogen, to give [Re(N2)(tipt)3(PPh3)] and [Re(N2)(dipbt)3(PPh3)], respectively in good yield, and under similar conditions 2,6-dimethylthiophenol (Hdmt) or 2,6-dimethoxythiophenol (Hdmot) gave [Re(dmt)3(PPh3)] and [Re(dmot)3(PPh3)] respectively; the complex [Re(dmt)3(PPh3)(PPh2H)] was also isolated from the same reaction with Hdmt.

引用

页码：551 / 553

页数：3

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