STRUCTURAL INVESTIGATION OF MOLECULAR-ORGANIZATION IN SELF-ASSEMBLED MONOLAYERS OF A SEMIFLUORINATED AMIDETHIOL

被引:202
作者
LENK, TJ
HALLMARK, VM
HOFFMANN, CL
RABOLT, JF
CASTNER, DG
ERDELEN, C
RINGSDORF, H
机构
[1] IBM CORP,DIV RES,ALMADEN RES CTR,SAN JOSE,CA 95120
[2] UNIV WASHINGTON,DEPT CHEM ENGN,SEATTLE,WA 98195
[3] UNIV MAINZ,INST ORGAN CHEM,W-6500 MAINZ,GERMANY
关键词
D O I
10.1021/la00024a037
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A new fluorocarbon-chain-containing molecule, CF3(CF2)(7)C(O)N(H)CH2CH2SH, for self-assembly was synthesized using a simple and general technique. Self-assembled monolayers of this molecule were studied using ellipsometry, contact angle measurements, grazing-incidence infrared spectroscopy, X-ray photoelectron spectroscopy, and near-edge X-ray absorption fine structure measurements. The films were found to be uniform and reproducible, presenting a fluorocarbon surface (theta(adv)(H2O) = 114 degrees) with predominantly CF3 groups exposed. The C=O and N-H dipoles are found to be oriented parallel to the gold surface, with the fluorocarbon axis oriented perpendicular to the surface.
引用
收藏
页码:4610 / 4617
页数:8
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