INTRAMOLECULAR NUCLEOPHILIC CATALYSIS OF GLUCOSIDE HYDROLYSIS BY THE 2-PHOSPHATE GROUP

被引：3

作者：

KIRBY, AJ

STROMBERG, R

机构：

[1] UNIV CAMBRIDGE,CHEM LAB,LENSFIELD RD,CAMBRIDGE CB2 1EW,ENGLAND

[2] UNIV STOCKHOLM,DEPT ORGAN CHEM,S-10691 STOCKHOLM,SWEDEN

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 06期

关键词：

D O I：

10.1039/c39940000709

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

4-Nitrophenyl beta-D-glucoside tetraphosphate is hydrolysed 100 times faster than the 2-methoxy derivative, by way of the 1,2-cyclic phosphate diester, which is solvolysed by attack at phosphorus.

引用

页码：709 / 710

页数：2

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