STRUCTURE AND PROPERTIES OF HYDROTHERMALLY SYNTHESIZED THIOSULFATE CANCRINITE

被引：19

作者：

LINDNER, GG

MASSA, W

REINEN, D

机构：

[1] UNIV MARBURG,FACHBEREICH CHEM,D-35032 MARBURG,GERMANY

[2] UNIV MARBURG,ZENTRUM MAT WISSENSCH,D-35032 MARBURG,GERMANY

来源：

JOURNAL OF SOLID STATE CHEMISTRY | 1995年 / 117卷 / 02期

关键词：

D O I：

10.1006/jssc.1995.1289

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Thiosulfate cancrinite was prepared by hydrothermal methods. The single crystal X-ray investigation yielded the space group P3 (n = 12.624(2) Angstrom, 5.170(1) A, R = 0.031, at 193 K). Axial twinning along [001] was observed. The thiosulfate anions show orientational disorder. On irradiation or heating, yellow to greenish-blue coloration occurs according to the formation of S-2(-) and SS radicals within the spacy channels of the cancrinite structure. These radicals are identified by UV/VIS and ESR spectroscopy, and a mechanism of formation is proposed. (C) 1995 Academic Press, Inc.

引用

页码：386 / 391

页数：6

共 20 条

[11] SYNTHETIC SULFATE HYDROCANCRINITE OF MICROSOMMIT TYPE [J].

KLASKA, R ;

JARCHOW, O .

NATURWISSENSCHAFTEN, 1977, 64 (02) :93-93

[12] SYNTHESIS, COLOR, AND STRUCTURE OF A RED SELENIUM ULTRAMARINE [J].

LINDNER, GG ;

REINEN, D .

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1994, 620 (07) :1321-1328

[13]

LINDNER GG, 1994, THESIS PHILIPPS U MA

[14]

PAHOR NB, 1982, ACTA CRYSTALLOGR B, V38, P893, DOI 10.1107/S0567740882004312

[15] STACKING VARIATIONS IN CANCRINITE MINERALS [J].

RINALDI, R ;

WENK, HR .

ACTA CRYSTALLOGRAPHICA SECTION A, 1979, 35 (SEP) :825-828

[16] ELECTRON SPIN RESONANCE OF SULFUR AND SELENIUM RADICALS IN ALKALI HALIDES [J].

SCHNEIDER, J ;

DISCHLER, B ;

RAUBER, A .

PHYSICA STATUS SOLIDI, 1966, 13 (01) :141-+

[17] PROBLEM OF THE COLORED SPECIES IN ULTRAMARINE GREEN AND ULTRAMARINE RED [J].

SEEL, F ;

GUTTLER, HJ ;

WIECKOWSKI, AB ;

WOLF, B .

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1979, 34 (12) :1671-1677

[18]

Seel F, 1984, STUDIES INORGANIC CH, V5, P67

[19]

SHELDRICK GM, 1993, SHELXL 93 PROGRAM RE

[20]

WEAST RC, 1985, HDB CHEM PHYSICS

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