ASYMMETRIZATION OF MESO 1,4-ENEDIOL ETHERS BY ISOMERIZATION WITH A CHIRAL BINAP-RH-I CATALYST

被引：78

作者：

HIROYA, K ^{[1
]}

KURIHARA, Y ^{[1
]}

OGASAWARA, K ^{[1
]}

机构：

[1] TOHOKU UNIV,INST PHARMACEUT,SENDAI,MIYAGI 98077,JAPAN

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1995年 / 34卷 / 20期

关键词：

ASYMMETRIC SYNTHESES; CATALYSIS; ISOMERIZATIONS; RHODIUM COMPOUNDS;

D O I：

10.1002/anie.199522871

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

High enantiomeric purities are achieved with the method described here for the transformation of meso 1,4‐enediol ethers such as 1 into oxyketones such as 2 in the presence of a chiral RhI catalyst. These products are versatile chiral building blocks in synthesis. TBS = tert‐butyldimethylsilyl. (Figure Presented.) Copyright © 1995 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：2287 / 2289

页数：3

共 28 条

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