ALPHA-METALATED TERTIARY ENOL CARBAMATES - NEW ACYL ANION EQUIVALENTS

被引：67

作者：

SENGUPTA, S ^{[1
]}

SNIECKUS, V ^{[1
]}

机构：

[1] UNIV WATERLOO,GUELPH WATERLOO CTR GRAD WORK CHEM,WATERLOO N2L 3G1,ONTARIO,CANADA

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1990年 / 55卷 / 22期

关键词：

D O I：

10.1021/jo00309a008

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

: α-Metalated enol carbamate lg constitutes a new, conveniently generated (sec-BuLi/TMEDA/THF/ -78 °C), and well-behaved acyl anion equivalent. The utility and scope of this synthon for the preparation of a variety of useful synthetic building blocks (4, 6, 8, 11, 12) has been demonstrated. © 1990, American Chemical Society. All rights reserved.

引用

页码：5680 / 5683

页数：4

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