MANGANESE(III)-PROMOTED FREE-RADICAL ADDITION OF DIMETHYL BROMOMALONATE TO OLEFINS USING AN ELECTROCHEMICAL REGENERATION PROCEDURE

被引：16

作者：

NEDELEC, JY

NOHAIR, K

机构：

[1] G.N.R.S., Laboratoire d'Elecfrochimie Catalyse et Synthèse Organique, UMR 28, 2 rue H. Dunant, Thiais

来源：

SYNLETT | 1991年 / 09期

关键词：

D O I：

10.1055/s-1991-20832

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The free-radical chain addition reaction of dimethyl bromomalonate onto olefins can be easily initiated by electrochemically in situ generated manganic salt used in catalytic amount, to give the 1:1 adduct (dimethyl 2-bromoalkylmalonates) in high chemical and faradaic yield at or near room temperature. The method illustrated here offers an interesting approach to carry out free-radical reactions under very simple reaction conditions.

引用

页码：659 / 660

页数：2

共 19 条

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