CYCLIC VOLTAMMETRIC AND ELECTROCRYSTALLIZATION STUDIES OF AXIALLY SUBSTITUTED BISCYANOPHTHALOCYANINATO METAL-COMPLEXES AND RELATED-COMPOUNDS

被引：35

作者：

BEHNISCH, R ^{[1
]}

HANACK, M ^{[1
]}

机构：

[1] UNIV TUBINGEN,LEHRSTUHL ORGAN CHEM 2,INST ORGAN CHEM,AUF MORGENSTELLE 18,W-7400 TUBINGEN 1,GERMANY

来源：

SYNTHETIC METALS | 1990年 / 36卷 / 03期

关键词：

D O I：

10.1016/0379-6779(90)90262-J

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Cyclic voltammetric studies of several biscyanophthalocyaninato metal complexes and related compounds A[Mc(-2)M(+III)(CN)2] (A = Na, K, Bu4N; Mc = macrocycle = phthalocyaninato, tetrabenzoporphyrinato, 2,3-naphthalocyaninato; M = Co, Rh, Fe, Ru, Cr, Mn) in acetone/0.1 M Bu4NClO4 indicated that the first oxidation process occurs on the macrocycle leading to an Mc(-1)M(+III)(CN)2 radical-cation species. By galvanostatic and potentiostatic electrocrystallization of the monomeric compounds A[Mc(-2)M(+III)X2] in acetone, the corresponding Mc(-1)M-(+III)X2 compounds could be synthesized. These compounds were characterized by IR, far-IR and UV-V is spectroscopy, as well as elemental analyses and mass spectrometry. In contrast to previous results, penta-coordinated compounds Mc(-2)M(+III)X were not observed in the electrocrystallization experiments. © 1990.

引用

页码：387 / 397

页数：11

共 45 条

[1] ANODIC CYANATIONS OF AROMATIC COMPOUNDS [J].