SYNTHESIS AND TRANSITION-TEMPERATURES OF SOME NOVEL, CHIRAL NEMATIC, LATERALLY ATTACHED, SIDE-CHAIN, SILOXANE POLYMERS

被引：37

作者：

LEWTHWAITE, RA ^{[1
]}

GRAY, GW ^{[1
]}

TOYNE, KJ ^{[1
]}

机构：

[1] UNIV HULL,SCH CHEM,HULL HU6 7RX,N HUMBERSIDE,ENGLAND

来源：

JOURNAL OF MATERIALS CHEMISTRY | 1992年 / 2卷 / 01期

关键词：

CHIRAL NEMATIC POLYMER; LATERALLY ATTACHED POLYSILOXANE; LIQUID CRYSTAL;

D O I：

10.1039/jm9920200119

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The synthesis of a chiral nematic, laterally attached polymer, from an enantiotropic chiral nematic side-chain precursor is described, and ways of achieving selective esterifications of 2,4-dihydroxybenzoates are discussed. This compound is the first example of its kind to exhibit the chiral nematic phase in both the monomer and the derived polymer; the results show that the polymer has a lower chiral nematic to isotropic clearing point than the monomer.

引用

页码：119 / 124

页数：6