A CONCISE BIOMIMETIC TOTAL SYNTHESIS OF (+/-)-TAXODIONE VIA A BF3.MENO2 PROMOTED CATIONIC CASCADE ANNULATION

被引：17

作者：

HARRING, SR ^{[1
]}

LIVINGHOUSE, T ^{[1
]}

机构：

[1] MONTANA STATE UNIV,DEPT CHEM & BIOCHEM,BOZEMAN,MT 59717

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 06期

关键词：

D O I：

10.1039/c39920000502

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A highly convergent seven-step total synthesis of the antineoplastic agent (+/-)-taxodione 1 is described which utilizes a cationic cascade cyclization mediated by BF3.MeNO2 complex.

引用

页码：502 / 503

页数：2

共 13 条

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[13] BENZOCYCLOBUTENONES AS SYNTHONS FOR THE SYNTHESIS OF C-11 OXYGENATED DITERPENOIDS - APPLICATION TO THE TOTAL SYNTHESIS OF (+/-)-TAXODIONE [J].

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