STRUCTURE OF (DIETHYLAMINO)(1-[(2-HYDROXYPHENYL)IMINOMETHYL]NAPHTHALEN-2-OLATO-0,0',N)NICKEL(II)

被引：15

作者：

ELERMAN, Y ^{[1
]}

FUESS, H ^{[1
]}

PAULUS, H ^{[1
]}

机构：

[1] TH DARMSTADT,FACHBEREICH MAT WISSENCH,FACHGEBIET STRUKTURFORSCH,W-6100 DARMSTADT,GERMANY

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1992年 / 48卷

关键词：

D O I：

10.1107/S010827019100447X

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

[Ni(C4H11N)(C17H11NO2)], M(r) = 393.11, monoclinic, P2(1)/n, a = 12.233 (4), b = 8.846 (3), c = 17.155 (6) angstrom, beta = 96.04 (1)-degrees, V = 1846.2 angstrom 3, Z = 4, D(x) = 1.414 g cm-3, lambda(MoK-alpha) = 0.71069 angstrom, mu = 10.41 cm-1, F(000) = 824, T = 298 K, final R = 0.035, wR = 0.030 for 2181 unique reflections with F > 2-sigma(F). The coordination of the Ni atom is square planar with Ni-O distances 1.820(3) and 1.842 (3) angstrom, Ni-N distances 1.849 (3) and 1.955 (4) angstrom; the angles between the neighbouring ligands are in the range 86.8 to 94.8 (1)-degrees. The diethylamino ligand is fully extended perpendicular to the Ni coordination plane.

引用

页码：40 / 42

页数：3

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