LANTHANOID(III) TRIFLATES AS NEW GLYCOSYLATION CATALYSTS - SELECTIVE AND EFFICIENT ACTIVATION OF 1-O-METHOXYACETYL SUGARS

被引:50
作者
INANAGA, J
YOKOYAMA, Y
HANAMOTO, T
机构
[1] Institute for Molecular Science, Okazaki, 444, Myodaiji
关键词
D O I
10.1016/S0040-4039(00)73563-5
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The reactions of 1-O-methoxyacetyl sugars with alcohols or thiols were effectively promoted by a catalytic amount of lanthanoid(III) triflates such as Tb(OTf)3, Ho(OTf)3, Tm(OTf)3, and Yb(OTf)3 to give the corresponding glycosides in good to excellent yields.
引用
收藏
页码:2791 / 2794
页数:4
相关论文
共 9 条