TELLURIUM AN INTERESTING BONDING PARTNER FOR TRANSITION-METALS - NEW RESULTS FROM MOLECULAR CHEMISTRY

被引：27

作者：

SIEMELING, U

机构：

[1] Fakultät Für Chemie, Universität Bielefeld, D-W-4800, Universitätsstrasse

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1993年 / 32卷 / 01期

关键词：

D O I：

10.1002/anie.199300671

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The first complexes with terminal tellurido ligands such as 1 - 3 were synthesized; analogous sulfido complexes have been known for a long time. These compounds were postulated as molecular intermediates for the known thermal decomposition of transition metal tellurolates into the corresponding tellurides. However, the homoleptic tellurolato complexes of Group 12 metals, which have likewise only recently been accessible, are also of interest as potential one-component precursors for II/VI semiconductors. M = Zr, Hf; R = Si(SiMe3)3.(~)[GRAPHICS]

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页码：67 / 68

页数：2

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