SYNTHESIS OF BUTENOLIDES VIA ENANTIOSELECTIVE DEPROTONATION OF PROTECTED 4-HYDROXYCYCLOHEXANONE

被引：22

作者：

MAJEWSKI, M

IRVINE, NM

MACKINNON, J

机构：

[1] Department of Chemistry, University of Saskatchewan, Saskatoon, Sask. S7N 5C9

来源：

TETRAHEDRON-ASYMMETRY | 1995年 / 6卷 / 08期

基金：

加拿大自然科学与工程研究理事会;

关键词：

D O I：

10.1016/0957-4166(95)00231-D

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Enantioselective synthesis of two butenolides (4S, 6R)-2,3-Dihydroaquilegiolide and (4S, 6S)-2,3-Dihydromenisdaurilide based on deprotonation of 4-tert-butyldimethyl-siloxycyclohexanone with a chiral lithium amide base is described.

引用

页码：1837 / 1840

页数：4

共 18 条

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