AN OPEN-FRAMEWORK ZINC PHOSPHATE WITH ZN-O-ZN LINKAGES

被引：74

作者：

SONG, TY

HURSTHOUSE, MB

CHEN, JH

XU, JN

MALIK, KMA

JONES, RH

XU, RR

THOMAS, JM

机构：

[1] UCL ROYAL INST GREAT BRITAIN, DAVY FARADAY RES LAB, 21 ALBEMARLE ST, LONDON W1X 4BS, ENGLAND

[2] JILIN UNIV, DEPT CHEM, CHANGCHUN, PEOPLES R CHINA

[3] UNIV WALES COLL CARDIFF, SCH CHEM & APPL CHEM, CARDIFF CF1 3TB, WALES

[4] UNIV KEELE, DEPT CHEM, KEELE ST5 5BG, STAFFS, ENGLAND

来源：

ADVANCED MATERIALS | 1994年 / 6卷 / 09期

关键词：

Amines - Crystallization - Ethylene - Glycols - Molecular structure - Phosphates - Porous materials - Zinc oxide;

D O I：

10.1002/adma.19940060914

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Open framework crystalline solids have great potential as catalysts and absorbers and for many other applications in materials science. The synthesis and structural characterization of a new zinc phosphate prepared from a predominantly non-aqueous system are described. The unique features of the compound, which has the empirical formula Zn4(PO4)3(H2O)(C2H5NH3), such as three-coordinated oxygen atoms and a ratio of Zn to P greater than 1, are discussed.

引用

页码：679 / 680

页数：2

共 18 条

[1]

CHEN J, 1994, ANGEW CHEM, V106, P667

[2]

CHEN JS, 1994, ANGEW CHEM INT EDIT, V33, P639, DOI 10.1002/anie.199406391

[3] A DIMERIC CALCIUM SILOXIDE LIGHTLY STABILIZED BY AMMONIA LIGANDS [J].

DARR, JA ;

DRAKE, SR ;

HURSTHOUSE, MB ;

MALIK, KMA .

INORGANIC CHEMISTRY, 1993, 32 (25) :5704-5708

[4]

EASTERMANN M, 1991, NATURE, V352, P320

[5]

HARRISON WA, COMMUNICATION

[6] TETRAHEDRAL-ATOM ZINCOPHOSPHATE STRUCTURES - SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF 2 NOVEL ANIONIC 8-RING FRAMEWORKS CONTAINING CATIONIC 1,4-DIAZABICYCLO[2.2.2]OCTANE GUESTS [J].

HARRISON, WTA ;

MARTIN, TE ;

GIER, TE ;

STUCKY, GD .

JOURNAL OF MATERIALS CHEMISTRY, 1992, 2 (02) :175-181

[7]

HARVEY G, 1988, Z KRISTALLOGR, V182, P123

[8] GENERALIZED SYNTHESIS OF PERIODIC SURFACTANT INORGANIC COMPOSITE-MATERIALS [J].

HUO, QS ;

MARGOLESE, DI ;

CIESLA, U ;

FENG, PY ;

GIER, TE ;

SIEGER, P ;

LEON, R ;

PETROFF, PM ;

SCHUTH, F ;

STUCKY, GD .

NATURE, 1994, 368 (6469) :317-321

[9]

JONES RH, 1992, CHEM MATER, V31, P213

[10]

Lowenstein W., 1954, AM MINERAL, V39, P92

← 1 2 →